TY - JOUR
T1 - Synthesis of neutral and cationic NHC-Au complexes as nanoparticle precursors
AU - Lomelí-Rosales, Diego Alberto
AU - Aguilar-Alcaraz, Alejandro
AU - Alvarado-Rodríguez, José Guadalupe
AU - Becerra-Martínez, Elvia
AU - Zamudio-Ojeda, Adalberto
AU - Velázquez-Juárez, Gilberto
AU - Rangel-Salas, Irma Idalia
AU - Peregrina-Lucano, Alejandro Aarón
AU - López-Reyes, Morelia E.
AU - Cortés-Llamas, Sara A.
N1 - Publisher Copyright:
© 2020
PY - 2020/5/15
Y1 - 2020/5/15
N2 - The synthesis of organometallic gold complexes with symmetric N-heterocyclic carbene ligand (NHC) derivatives derived from 2-(methylthio)aniline is reported. These complexes were obtained as either molecular monocarbene complexes [Au(NHC)Cl], [Au(NHC)Cl3], and [Au(NHC)Br3]) or cationic biscarbene complex [Au(NHC)2]PF6. These compounds were tested as gold nanoparticle precursors that were stabilized by the corresponding NHC ligand.
AB - The synthesis of organometallic gold complexes with symmetric N-heterocyclic carbene ligand (NHC) derivatives derived from 2-(methylthio)aniline is reported. These complexes were obtained as either molecular monocarbene complexes [Au(NHC)Cl], [Au(NHC)Cl3], and [Au(NHC)Br3]) or cationic biscarbene complex [Au(NHC)2]PF6. These compounds were tested as gold nanoparticle precursors that were stabilized by the corresponding NHC ligand.
UR - http://www.scopus.com/inward/record.url?scp=85081649421&partnerID=8YFLogxK
U2 - 10.1016/j.poly.2020.114476
DO - 10.1016/j.poly.2020.114476
M3 - Artículo
AN - SCOPUS:85081649421
SN - 0277-5387
VL - 182
JO - Polyhedron
JF - Polyhedron
M1 - 114476
ER -