Synthesis of neutral and cationic NHC-Au complexes as nanoparticle precursors

Diego Alberto Lomelí-Rosales, Alejandro Aguilar-Alcaraz, José Guadalupe Alvarado-Rodríguez, Elvia Becerra-Martínez, Adalberto Zamudio-Ojeda, Gilberto Velázquez-Juárez, Irma Idalia Rangel-Salas, Alejandro Aarón Peregrina-Lucano, Morelia E. López-Reyes, Sara A. Cortés-Llamas

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Resumen

The synthesis of organometallic gold complexes with symmetric N-heterocyclic carbene ligand (NHC) derivatives derived from 2-(methylthio)aniline is reported. These complexes were obtained as either molecular monocarbene complexes [Au(NHC)Cl], [Au(NHC)Cl3], and [Au(NHC)Br3]) or cationic biscarbene complex [Au(NHC)2]PF6. These compounds were tested as gold nanoparticle precursors that were stabilized by the corresponding NHC ligand.

Idioma originalInglés
Número de artículo114476
PublicaciónPolyhedron
Volumen182
DOI
EstadoPublicada - 15 may. 2020

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