TY - JOUR
T1 - Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipyridyl ligands
AU - Andrade-López, Noemí
AU - Alvarado-Rodríguez, José G.
AU - González-Montiel, Simplicio
AU - Páez-Hernández, María Elena
AU - Galán-Vidal, Carlos Andrés
AU - Jiménez-Pérez, Araceli
PY - 2008
Y1 - 2008
N2 - Coordinative behavior of the di-(2-pyridyl)hydroxymethane (1) and di-(2-pyridyl)-2-pyridylsulfanylmethane (2) ligands towards Pd(II) and Pt(II) is described. The compounds 3-5 were characterized by IR, mass spectrometry and NMR spectroscopy. Crystal structures of [Pt{(C5H4N) 2CH(OH)}Cl2] 3 and [Pd{(C5H4N) 2CH(2-C5H4NS)}Cl2] 4 as DMSO solvates displayed the formation of neutral mononuclear complexes. In the complexes 3 and 4 is observed the formation of six-membered chelate rings. The local geometry of the metallic atoms can be described as square planar in the title complexes.
AB - Coordinative behavior of the di-(2-pyridyl)hydroxymethane (1) and di-(2-pyridyl)-2-pyridylsulfanylmethane (2) ligands towards Pd(II) and Pt(II) is described. The compounds 3-5 were characterized by IR, mass spectrometry and NMR spectroscopy. Crystal structures of [Pt{(C5H4N) 2CH(OH)}Cl2] 3 and [Pd{(C5H4N) 2CH(2-C5H4NS)}Cl2] 4 as DMSO solvates displayed the formation of neutral mononuclear complexes. In the complexes 3 and 4 is observed the formation of six-membered chelate rings. The local geometry of the metallic atoms can be described as square planar in the title complexes.
KW - NMR
KW - Pd(II) and Pt(II) complexes
KW - X ray diffraction
KW - di-(2-pyridyl)-2-pyridylsulfanylmethane
KW - di-(2-pyridyl)hydroxymethane
UR - http://www.scopus.com/inward/record.url?scp=40849092914&partnerID=8YFLogxK
U2 - 10.3998/ark.5550190.0009.505
DO - 10.3998/ark.5550190.0009.505
M3 - Artículo
SN - 1551-7012
VL - 2008
SP - 43
EP - 54
JO - Arkivoc
JF - Arkivoc
IS - 5
ER -