Reactivity of [H2Os3(CO)10] with six-membered heterocycles containing sulfur and/or nitrogen atoms. Cleavage of C-S, C-N and C-H bonds to yield linked clusters with S-C, and S-C-N bridging fragments

Ottmar Reyes-López; Sonia A. Sánchez-Ruiz; Angelina Flores-Parra; Marco A. Leyva; Rodrigo J. Alvarez-Méndez; Alberto Vela; María J. Rosales-Hoz

doi:10.1016/j.jorganchem.2014.09.012

Reactivity of [H₂Os₃(CO)₁₀] with six-membered heterocycles containing sulfur and/or nitrogen atoms. Cleavage of C-S, C-N and C-H bonds to yield linked clusters with S-C, and S-C-N bridging fragments

Ottmar Reyes-López, Sonia A. Sánchez-Ruiz, Angelina Flores-Parra, Marco A. Leyva, Rodrigo J. Alvarez-Méndez, Alberto Vela, María J. Rosales-Hoz

Unidad Profesional Interdisciplinaria de Ingeniería y Tecnologías Avanzadas (UPIITA)

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

5 Citas (Scopus)

Resumen

The reactions of [H₂Os₃(CO)₁₀] with hetero-cyclohexanes with positions 1, 3 and 5 substituted by nitrogen or sulfur atoms; 1,3,5-trimethyl-1,3,5-triazinane, 3,5-dimethyl-1,3,5-thiadiazinane, 5-methyl-1,3,5-dithiazinane and 1,3,5-trithiane; produce compounds where sulfur atoms and NCN fragments bridge metal-metal bonds as well as complexes containing trinuclear metal fragments linked by SCS and SCNCS units. Spectroscopic characterization of the products as well as the X-ray crystal structures of complexes {[(μ-H)Os₃(CO)₉(PMe₃)]-[μ-(H₂CCS₂)]-[(μ-H)Os₃(CO)₁₀]}, {(μ-H)Os₃(CO)₁₀(μ-SCH₂NMe₂)}, {[(μ-H)Os₃(CO)₁₀]₂[μ-S₂(CH₂)₂NMe]} and [Os(S₃(CH₂)₃)₂Cl₂(CO)₂] are reported. A mechanistic proposal for all the reactions is made based in spectroscopic analysis of the reaction mixtures and theoretical calculations for the non-coordinated ligands.

Idioma original	Inglés
Páginas (desde-hasta)	248-257
Número de páginas	10
Publicación	Journal of Organometallic Chemistry
Volumen	772
DOI	https://doi.org/10.1016/j.jorganchem.2014.09.012
Estado	Publicada - 1 dic. 2014

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10.1016/j.jorganchem.2014.09.012

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Reyes-López, O., Sánchez-Ruiz, S. A., Flores-Parra, A., Leyva, M. A., Alvarez-Méndez, R. J., Vela, A., & Rosales-Hoz, M. J. (2014). Reactivity of [H₂Os₃(CO)₁₀] with six-membered heterocycles containing sulfur and/or nitrogen atoms. Cleavage of C-S, C-N and C-H bonds to yield linked clusters with S-C, and S-C-N bridging fragments. Journal of Organometallic Chemistry, 772, 248-257. https://doi.org/10.1016/j.jorganchem.2014.09.012

@article{935a702292ee40a49ee59ecf6e54c742,

title = "Reactivity of [H2Os3(CO)10] with six-membered heterocycles containing sulfur and/or nitrogen atoms. Cleavage of C-S, C-N and C-H bonds to yield linked clusters with S-C, and S-C-N bridging fragments",

abstract = "The reactions of [H2Os3(CO)10] with hetero-cyclohexanes with positions 1, 3 and 5 substituted by nitrogen or sulfur atoms; 1,3,5-trimethyl-1,3,5-triazinane, 3,5-dimethyl-1,3,5-thiadiazinane, 5-methyl-1,3,5-dithiazinane and 1,3,5-trithiane; produce compounds where sulfur atoms and NCN fragments bridge metal-metal bonds as well as complexes containing trinuclear metal fragments linked by SCS and SCNCS units. Spectroscopic characterization of the products as well as the X-ray crystal structures of complexes {[(μ-H)Os3(CO)9(PMe3)]-[μ-(H2CCS2)]-[(μ-H)Os3(CO)10]}, {(μ-H)Os3(CO)10(μ-SCH2NMe2)}, {[(μ-H)Os3(CO)10]2[μ-S2(CH2)2NMe]} and [Os(S3(CH2)3)2Cl2(CO)2] are reported. A mechanistic proposal for all the reactions is made based in spectroscopic analysis of the reaction mixtures and theoretical calculations for the non-coordinated ligands.",

keywords = "Cleavage C-N and C-S bonds, Heterocyclohexanes, Trinuclear osmium clusters",

author = "Ottmar Reyes-L{\'o}pez and S{\'a}nchez-Ruiz, {Sonia A.} and Angelina Flores-Parra and Leyva, {Marco A.} and Alvarez-M{\'e}ndez, {Rodrigo J.} and Alberto Vela and Rosales-Hoz, {Mar{\'i}a J.}",

note = "Publisher Copyright: {\textcopyright} 2014 Elsevier B.V.",

year = "2014",

month = dec,

day = "1",

doi = "10.1016/j.jorganchem.2014.09.012",

language = "Ingl{\'e}s",

volume = "772",

pages = "248--257",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

}

Reyes-López, O, Sánchez-Ruiz, SA, Flores-Parra, A, Leyva, MA, Alvarez-Méndez, RJ, Vela, A & Rosales-Hoz, MJ 2014, 'Reactivity of [H₂Os₃(CO)₁₀] with six-membered heterocycles containing sulfur and/or nitrogen atoms. Cleavage of C-S, C-N and C-H bonds to yield linked clusters with S-C, and S-C-N bridging fragments', Journal of Organometallic Chemistry, vol. 772, pp. 248-257. https://doi.org/10.1016/j.jorganchem.2014.09.012

Reactivity of [H₂Os₃(CO)₁₀] with six-membered heterocycles containing sulfur and/or nitrogen atoms. Cleavage of C-S, C-N and C-H bonds to yield linked clusters with S-C, and S-C-N bridging fragments. / Reyes-López, Ottmar; Sánchez-Ruiz, Sonia A.; Flores-Parra, Angelina et al.
En: Journal of Organometallic Chemistry, Vol. 772, 01.12.2014, p. 248-257.

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

TY - JOUR

T1 - Reactivity of [H2Os3(CO)10] with six-membered heterocycles containing sulfur and/or nitrogen atoms. Cleavage of C-S, C-N and C-H bonds to yield linked clusters with S-C, and S-C-N bridging fragments

AU - Reyes-López, Ottmar

AU - Sánchez-Ruiz, Sonia A.

AU - Flores-Parra, Angelina

AU - Leyva, Marco A.

AU - Alvarez-Méndez, Rodrigo J.

AU - Vela, Alberto

AU - Rosales-Hoz, María J.

PY - 2014/12/1

Y1 - 2014/12/1

N2 - The reactions of [H2Os3(CO)10] with hetero-cyclohexanes with positions 1, 3 and 5 substituted by nitrogen or sulfur atoms; 1,3,5-trimethyl-1,3,5-triazinane, 3,5-dimethyl-1,3,5-thiadiazinane, 5-methyl-1,3,5-dithiazinane and 1,3,5-trithiane; produce compounds where sulfur atoms and NCN fragments bridge metal-metal bonds as well as complexes containing trinuclear metal fragments linked by SCS and SCNCS units. Spectroscopic characterization of the products as well as the X-ray crystal structures of complexes {[(μ-H)Os3(CO)9(PMe3)]-[μ-(H2CCS2)]-[(μ-H)Os3(CO)10]}, {(μ-H)Os3(CO)10(μ-SCH2NMe2)}, {[(μ-H)Os3(CO)10]2[μ-S2(CH2)2NMe]} and [Os(S3(CH2)3)2Cl2(CO)2] are reported. A mechanistic proposal for all the reactions is made based in spectroscopic analysis of the reaction mixtures and theoretical calculations for the non-coordinated ligands.

AB - The reactions of [H2Os3(CO)10] with hetero-cyclohexanes with positions 1, 3 and 5 substituted by nitrogen or sulfur atoms; 1,3,5-trimethyl-1,3,5-triazinane, 3,5-dimethyl-1,3,5-thiadiazinane, 5-methyl-1,3,5-dithiazinane and 1,3,5-trithiane; produce compounds where sulfur atoms and NCN fragments bridge metal-metal bonds as well as complexes containing trinuclear metal fragments linked by SCS and SCNCS units. Spectroscopic characterization of the products as well as the X-ray crystal structures of complexes {[(μ-H)Os3(CO)9(PMe3)]-[μ-(H2CCS2)]-[(μ-H)Os3(CO)10]}, {(μ-H)Os3(CO)10(μ-SCH2NMe2)}, {[(μ-H)Os3(CO)10]2[μ-S2(CH2)2NMe]} and [Os(S3(CH2)3)2Cl2(CO)2] are reported. A mechanistic proposal for all the reactions is made based in spectroscopic analysis of the reaction mixtures and theoretical calculations for the non-coordinated ligands.

KW - Cleavage C-N and C-S bonds

KW - Heterocyclohexanes

KW - Trinuclear osmium clusters

UR - http://www.scopus.com/inward/record.url?scp=84908011254&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2014.09.012

DO - 10.1016/j.jorganchem.2014.09.012

M3 - Artículo

AN - SCOPUS:84908011254

SN - 0022-328X

VL - 772

SP - 248

EP - 257

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Reyes-López O, Sánchez-Ruiz SA, Flores-Parra A, Leyva MA, Alvarez-Méndez RJ, Vela A et al. Reactivity of [H₂Os₃(CO)₁₀] with six-membered heterocycles containing sulfur and/or nitrogen atoms. Cleavage of C-S, C-N and C-H bonds to yield linked clusters with S-C, and S-C-N bridging fragments. Journal of Organometallic Chemistry. 2014 dic. 1;772:248-257. doi: 10.1016/j.jorganchem.2014.09.012