Photocatalytic hydrogen production using bimetallic and trimetallic hydrotalcite as photocatalysts

Y. Piña-Pérez; J. E. Samaniego-Benitez; F. Tzompantzi; L. Lartundo-Rojas; A. Garcia-Garcia; A. Mantilla; G. Romero-Ortiz

doi:10.1016/j.matlet.2022.133205

Photocatalytic hydrogen production using bimetallic and trimetallic hydrotalcite as photocatalysts

Y. Piña-Pérez, J. E. Samaniego-Benitez, F. Tzompantzi, L. Lartundo-Rojas, A. Garcia-Garcia, A. Mantilla, G. Romero-Ortiz

Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada (CICATA), Unidad Legaria

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

Resumen

Bimetallic ZnAl and trimetallic ZnCuAl hydrotalcites were synthesized using the coprecipitation method. The presence of the characteristic peaks of layered double hydroxide phases was observed by XRD analysis, as well as the typical like flower morphology of these materials by FESEM and HRTEM analysis. Changes in the valence and conduction bands position, as well as in the band gap calculated by UV–vis spectroscopy and XPS techniques was noted by the presence of Cu in the material. In the photocatalytic behavior for H₂ production in presence of UV irradiation, ZnCuAl hydrotalcite showed the highest yield of H₂ in comparison to ZnAl material, being both photocatalysts more actives that the reference photocatalyst, consisting in commercial TiO₂ (Degussa P-25).

Idioma original	Inglés
Número de artículo	133205
Publicación	Materials Letters
Volumen	330
DOI	https://doi.org/10.1016/j.matlet.2022.133205
Estado	Publicada - 1 ene. 2023

ODS de las Naciones Unidas

Este resultado contribuye a los siguientes Objetivos de Desarrollo Sostenible

Acceder al documento

10.1016/j.matlet.2022.133205

Otros archivos y enlaces

Enlace a la publicación en Scopus

Citar esto

@article{88a44d39114d4f499d4827b15e841ed2,

title = "Photocatalytic hydrogen production using bimetallic and trimetallic hydrotalcite as photocatalysts",

abstract = "Bimetallic ZnAl and trimetallic ZnCuAl hydrotalcites were synthesized using the coprecipitation method. The presence of the characteristic peaks of layered double hydroxide phases was observed by XRD analysis, as well as the typical like flower morphology of these materials by FESEM and HRTEM analysis. Changes in the valence and conduction bands position, as well as in the band gap calculated by UV–vis spectroscopy and XPS techniques was noted by the presence of Cu in the material. In the photocatalytic behavior for H2 production in presence of UV irradiation, ZnCuAl hydrotalcite showed the highest yield of H2 in comparison to ZnAl material, being both photocatalysts more actives that the reference photocatalyst, consisting in commercial TiO2 (Degussa P-25).",

keywords = "H production, Hydrotalcites, Photocatalysis",

author = "Y. Pi{\~n}a-P{\'e}rez and Samaniego-Benitez, {J. E.} and F. Tzompantzi and L. Lartundo-Rojas and A. Garcia-Garcia and A. Mantilla and G. Romero-Ortiz",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2023",

month = jan,

day = "1",

doi = "10.1016/j.matlet.2022.133205",

language = "Ingl{\'e}s",

volume = "330",

journal = "Materials Letters",

issn = "0167-577X",

}

TY - JOUR

T1 - Photocatalytic hydrogen production using bimetallic and trimetallic hydrotalcite as photocatalysts

AU - Piña-Pérez, Y.

AU - Samaniego-Benitez, J. E.

AU - Tzompantzi, F.

AU - Lartundo-Rojas, L.

AU - Garcia-Garcia, A.

AU - Mantilla, A.

AU - Romero-Ortiz, G.

PY - 2023/1/1

Y1 - 2023/1/1

N2 - Bimetallic ZnAl and trimetallic ZnCuAl hydrotalcites were synthesized using the coprecipitation method. The presence of the characteristic peaks of layered double hydroxide phases was observed by XRD analysis, as well as the typical like flower morphology of these materials by FESEM and HRTEM analysis. Changes in the valence and conduction bands position, as well as in the band gap calculated by UV–vis spectroscopy and XPS techniques was noted by the presence of Cu in the material. In the photocatalytic behavior for H2 production in presence of UV irradiation, ZnCuAl hydrotalcite showed the highest yield of H2 in comparison to ZnAl material, being both photocatalysts more actives that the reference photocatalyst, consisting in commercial TiO2 (Degussa P-25).

AB - Bimetallic ZnAl and trimetallic ZnCuAl hydrotalcites were synthesized using the coprecipitation method. The presence of the characteristic peaks of layered double hydroxide phases was observed by XRD analysis, as well as the typical like flower morphology of these materials by FESEM and HRTEM analysis. Changes in the valence and conduction bands position, as well as in the band gap calculated by UV–vis spectroscopy and XPS techniques was noted by the presence of Cu in the material. In the photocatalytic behavior for H2 production in presence of UV irradiation, ZnCuAl hydrotalcite showed the highest yield of H2 in comparison to ZnAl material, being both photocatalysts more actives that the reference photocatalyst, consisting in commercial TiO2 (Degussa P-25).

KW - H production

KW - Hydrotalcites

KW - Photocatalysis

UR - http://www.scopus.com/inward/record.url?scp=85140142972&partnerID=8YFLogxK

U2 - 10.1016/j.matlet.2022.133205

DO - 10.1016/j.matlet.2022.133205

M3 - Artículo

AN - SCOPUS:85140142972

SN - 0167-577X

VL - 330

JO - Materials Letters

JF - Materials Letters

M1 - 133205

ER -

Photocatalytic hydrogen production using bimetallic and trimetallic hydrotalcite as photocatalysts

Resumen

ODS de las Naciones Unidas

Acceder al documento

Otros archivos y enlaces

Huella

Citar esto