Resumen
Various experimental tests were conducted in a fixed-bed pilot plant in order to study the liquid phase sulfiding of a NiMo commercial catalyst. Four sulfiding feeds were employed in the present work: SRGO, SRGO + 1 wt.% sulfur DMDS, HDS-SRGO + 1 wt.% sulfur DMDS, and HDS-SRGO + 1.7 wt.% sulfur DMDS. Three sulfiding temperatures were evaluated: 290, 320, and 350°C. Drying and soaking of the catalyst were carried out before presulfiding. Each sulfided catalyst was evaluated in the hydrotreating of SRGO at the following conditions: 54 kg/cm2 pressure, 2.0 h-1 LHSV, 2000 ft3/bbl H2-to-oil ratio, and temperature of 340-380°C. SRGO + 1 wt.% sulfur DMDS was the best sulfiding feed. The catalyst sulfided at high temperature exhibited better activity. It was found that about 50% of the carbon on the catalyst after reaction is deposited during sulfiding step.
Idioma original | Inglés |
---|---|
Páginas (desde-hasta) | 75-81 |
Número de páginas | 7 |
Publicación | Catalysis Today |
Volumen | 98 |
N.º | 1-2 SPEC. ISS. |
DOI | |
Estado | Publicada - 24 nov. 2004 |
Publicado de forma externa | Sí |