TY - JOUR
T1 - Mg3[M(CN)6]2·xH2O with M = Fe, Co
T2 - Synthesis, crystal structure, and hydrogen sorption
AU - Jiménez-Gallegos, Juan
AU - Roque, Jorge
AU - Yee-Madeira, Hernani
AU - Reguera, Edilso
PY - 2012/6
Y1 - 2012/6
N2 - The titled materials were obtained neutralizing in situ prepared aqueous solutions of H3[M(CN)6] (M = Fe, Co) by adding Mg(OH) 2 and evaporating the solvent under vacuum. Their crystal structure was solved and refined from powder X-ray diffraction data. The two solids crystallize with a cubic unit cell, in the Pm$\bar{3}$m space group, which corresponds to an ordered distribution of [M(CN)6] vacancies. The materials structure is preserved when the crystal water is removed by moderated heating. The formed open porous framework was evaluated from nitrogen and hydrogen adsorption isotherms. The amount of hydrogen adsorbed is similar to that found for transition metal Prussian blue analogues. The structural study was complemented with infrared, thermo-gravimetric, and Mössbauer spectroscopy data.
AB - The titled materials were obtained neutralizing in situ prepared aqueous solutions of H3[M(CN)6] (M = Fe, Co) by adding Mg(OH) 2 and evaporating the solvent under vacuum. Their crystal structure was solved and refined from powder X-ray diffraction data. The two solids crystallize with a cubic unit cell, in the Pm$\bar{3}$m space group, which corresponds to an ordered distribution of [M(CN)6] vacancies. The materials structure is preserved when the crystal water is removed by moderated heating. The formed open porous framework was evaluated from nitrogen and hydrogen adsorption isotherms. The amount of hydrogen adsorbed is similar to that found for transition metal Prussian blue analogues. The structural study was complemented with infrared, thermo-gravimetric, and Mössbauer spectroscopy data.
KW - Crystal structure
KW - Hydrogen storage
KW - Magnesium
KW - Porous solids
KW - Prussian blue analogues
UR - http://www.scopus.com/inward/record.url?scp=84862649394&partnerID=8YFLogxK
U2 - 10.1002/zaac.201200028
DO - 10.1002/zaac.201200028
M3 - Artículo
SN - 0044-2313
VL - 638
SP - 1146
EP - 1150
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 7-8
ER -