TY - JOUR
T1 - Effect of plasmon–phonon interaction on the infrared reflection spectra of MgxZn1-xO/Al2O3 structures
AU - Melnichuk, O.
AU - Melnichuk, L.
AU - Venger, Ye
AU - Torchynska, T.
AU - Korsunska, N.
AU - Khomenkova, L.
N1 - Publisher Copyright:
© 2020, Springer Science+Business Media, LLC, part of Springer Nature.
PY - 2020/5/1
Y1 - 2020/5/1
N2 - The effect of plasmon–phonon interaction on the vibrational properties of the MgxZn1-xO films on anisotropic substrate is studied versus Mg content (x), film thickness (0.5–20 μm), free carrier concentration (1×1016–5×1018 cm−3) and damping coefficients using infrared reflection spectroscopy. The mathematical model with additive and phenomenological contribution of several oscillators to dielectric permittivity of MgxZn1-xO material was developed. The infrared reflection spectra were simulated in the range of “residual rays” of the film and the substrate for MgxZn1-xO/Al2O3 structures using self-consisted parameters of bulk ZnO, MgO and Al2O3 materials. Based on the Kramers–Kronig relationship, the frequency range where film reflectivity is sensitive to the variation of film doping and thickness was determined. The frequencies and damping coefficients of TO and LO modes of the oscillators, static and high-frequency dielectric permittivity for orientation E⊥c were obtained with high accuracy. Main attention was paid to the compositions which were in hexagonal structure. Experimental infrared reflection spectra were recorded for the films with x = 0.25 additionally doped with manganese and their simulation was performed based on the model developed. The free carrier concentration and mobility as well as film conductivity were determined. The results obtained showed the utility of infrared reflection spectroscopy for the investigation of textured alloy films. This non-destructive and contactless method can be implemented for the determination of optical properties of other semiconductor films.
AB - The effect of plasmon–phonon interaction on the vibrational properties of the MgxZn1-xO films on anisotropic substrate is studied versus Mg content (x), film thickness (0.5–20 μm), free carrier concentration (1×1016–5×1018 cm−3) and damping coefficients using infrared reflection spectroscopy. The mathematical model with additive and phenomenological contribution of several oscillators to dielectric permittivity of MgxZn1-xO material was developed. The infrared reflection spectra were simulated in the range of “residual rays” of the film and the substrate for MgxZn1-xO/Al2O3 structures using self-consisted parameters of bulk ZnO, MgO and Al2O3 materials. Based on the Kramers–Kronig relationship, the frequency range where film reflectivity is sensitive to the variation of film doping and thickness was determined. The frequencies and damping coefficients of TO and LO modes of the oscillators, static and high-frequency dielectric permittivity for orientation E⊥c were obtained with high accuracy. Main attention was paid to the compositions which were in hexagonal structure. Experimental infrared reflection spectra were recorded for the films with x = 0.25 additionally doped with manganese and their simulation was performed based on the model developed. The free carrier concentration and mobility as well as film conductivity were determined. The results obtained showed the utility of infrared reflection spectroscopy for the investigation of textured alloy films. This non-destructive and contactless method can be implemented for the determination of optical properties of other semiconductor films.
UR - http://www.scopus.com/inward/record.url?scp=85081349494&partnerID=8YFLogxK
U2 - 10.1007/s10854-020-03110-6
DO - 10.1007/s10854-020-03110-6
M3 - Artículo
AN - SCOPUS:85081349494
SN - 0957-4522
VL - 31
SP - 7539
EP - 7546
JO - Journal of Materials Science: Materials in Electronics
JF - Journal of Materials Science: Materials in Electronics
IS - 10
ER -