TY - JOUR
T1 - BiOBrxI1−x/BiOBr heterostructure engineering for efficient molecular oxygen activation
AU - Bai, Yang
AU - Shi, Xian
AU - Wang, Pingquan
AU - Wnag, Li
AU - Zhang, Kai
AU - Zhou, Ying
AU - Xie, Haiquan
AU - Wang, Jinan
AU - Ye, Liqun
N1 - Publisher Copyright:
© 2018 Elsevier B.V.
PY - 2019/1/15
Y1 - 2019/1/15
N2 - The BiOBrxI1−x/BiOBr heterojunction structural photocatalyst was constructed successfully in this work and it was formed by the BiOBrxI1−x solid solution coupling with the BiOBr monomer, which was determined by efficient characterizations. For the photocatalytic property, The BiOBrxI1−x/BiOBr could degrade some organic pollutants efficiently and the oilfield produced waste water treatment efficiency of it was ideal. The reason for its enhanced photocatalytic property was also explored. Through ESR tests, trapping experiments and other efficient methods, the enhanced molecular oxygen activation capacity of induced 1O2 and O2[rad]− photogeneration by BiOBrxI1−x solid solution structure and heterostructure in one photocatalyst was confirmed, respectively. This work provided a new thought for enhanced molecular oxygen activation capacity of bismuth oxyhalide photocatalysts.
AB - The BiOBrxI1−x/BiOBr heterojunction structural photocatalyst was constructed successfully in this work and it was formed by the BiOBrxI1−x solid solution coupling with the BiOBr monomer, which was determined by efficient characterizations. For the photocatalytic property, The BiOBrxI1−x/BiOBr could degrade some organic pollutants efficiently and the oilfield produced waste water treatment efficiency of it was ideal. The reason for its enhanced photocatalytic property was also explored. Through ESR tests, trapping experiments and other efficient methods, the enhanced molecular oxygen activation capacity of induced 1O2 and O2[rad]− photogeneration by BiOBrxI1−x solid solution structure and heterostructure in one photocatalyst was confirmed, respectively. This work provided a new thought for enhanced molecular oxygen activation capacity of bismuth oxyhalide photocatalysts.
KW - BiOBrI/BiOBr
KW - Environmental remediation
KW - Molecular oxygen activation
KW - Synergistic effect
UR - http://www.scopus.com/inward/record.url?scp=85052880746&partnerID=8YFLogxK
U2 - 10.1016/j.cej.2018.09.006
DO - 10.1016/j.cej.2018.09.006
M3 - Artículo
SN - 1385-8947
VL - 356
SP - 34
EP - 42
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
ER -