TY - JOUR
T1 - Addition of galactomannans and citric acid in corn starch processed by extrusion
T2 - Retrogradation and resistant starch studies
AU - von Borries-Medrano, Erich
AU - Jaime-Fonseca, Mónica R.
AU - Aguilar-Méndez, Miguel A.
AU - García-Cruz, Héctor I.
N1 - Publisher Copyright:
© 2018 Elsevier Ltd
PY - 2018/10
Y1 - 2018/10
N2 - Starch-galactomannan mixtures were elaborated by extrusion using a general factorial statistic design with three variables: galactomannan type (guar gum, tara gum and locust bean gum) at 10% (w/w), citric acid concentration (0‒2.5% w/w) and storage time at 4 °C (0‒7 days). Galactomannan type, citric acid concentration and storage time were factors that affected the physicochemical properties and microstructure of extrudates. Crystallinity of starch-guar gum extruded samples was higher compared with the samples obtained with the addition of the other gums and presented a variation from 3.38 ± 0.16 to 6.68 ± 0.23 when citric acid was added and stored at 4 °C and showed a correlation between long-range order (X-ray diffraction) and short-range order (FTIR). These results demonstrated the influence of the different galactomannans, the addition of citric acid and the storage at 4 ºC of the samples, which resulted in an increase in the formation of V-type amorphous structures. The DSC analysis demonstrated the formation of amylose-lipid complexes in which transitions temperatures started at above 90 °C, these structures may slow retrogradation rates of samples. In addition, these complexes can act as a part of resistant starch found in samples, which varies from 4.64 ± 0.15 to 12.13 ± 0.30 g/100 g sample in different extrudates. Overall, galactomannan type, citric acid concentration and storage time were factors that significantly affected the properties and resistant starch content of extruded samples.
AB - Starch-galactomannan mixtures were elaborated by extrusion using a general factorial statistic design with three variables: galactomannan type (guar gum, tara gum and locust bean gum) at 10% (w/w), citric acid concentration (0‒2.5% w/w) and storage time at 4 °C (0‒7 days). Galactomannan type, citric acid concentration and storage time were factors that affected the physicochemical properties and microstructure of extrudates. Crystallinity of starch-guar gum extruded samples was higher compared with the samples obtained with the addition of the other gums and presented a variation from 3.38 ± 0.16 to 6.68 ± 0.23 when citric acid was added and stored at 4 °C and showed a correlation between long-range order (X-ray diffraction) and short-range order (FTIR). These results demonstrated the influence of the different galactomannans, the addition of citric acid and the storage at 4 ºC of the samples, which resulted in an increase in the formation of V-type amorphous structures. The DSC analysis demonstrated the formation of amylose-lipid complexes in which transitions temperatures started at above 90 °C, these structures may slow retrogradation rates of samples. In addition, these complexes can act as a part of resistant starch found in samples, which varies from 4.64 ± 0.15 to 12.13 ± 0.30 g/100 g sample in different extrudates. Overall, galactomannan type, citric acid concentration and storage time were factors that significantly affected the properties and resistant starch content of extruded samples.
KW - Citric acid
KW - Corn starch
KW - Extrusion
KW - Galactomannans
KW - Resistant starch
KW - Retrogradation
UR - http://www.scopus.com/inward/record.url?scp=85043491552&partnerID=8YFLogxK
U2 - 10.1016/j.foodhyd.2018.03.009
DO - 10.1016/j.foodhyd.2018.03.009
M3 - Artículo
SN - 0268-005X
VL - 83
SP - 485
EP - 496
JO - Food Hydrocolloids
JF - Food Hydrocolloids
ER -