A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C<inf>5</inf>H<inf>4</inf>N-2-CH<inf>3</inf>C=N-(CH<inf>2</inf>)<inf>3</inf>NH<inf>2</inf>]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke!

J. Roberto Pioquinto-Mendoza, Patricia Conelly-Espinosa, Reyna Reyes-Martínez, Rubén A. Toscano, Juan M. Germán-Acacio, Alcives Avila-Sorrosa, Oscar Baldovino-Pantaleón, David Morales-Morales

Resultado de la investigación: Contribución a una revistaArtículo

7 Citas (Scopus)

Resumen

© 2015 Elsevier B.V. All rights reserved. The facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N<inf>1</inf>-(1-(pyridin-2-yl)ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species [Pd(L1)Cl][BF<inf>4</inf>] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a κ<sup>3</sup>-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki-Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks.
Idioma originalInglés estadounidense
Páginas (desde-hasta)153-158
Número de páginas137
PublicaciónJournal of Organometallic Chemistry
DOI
EstadoPublicada - 15 nov 2015

Huella dactilar

Imines
imines
Ligands
Propane
ligands
Diamines
evaluation
diamines
Molecular Structure
X-Ray Diffraction
propane
Molecular structure
Hydrogen
Hydrogen bonds
molecular structure
Single crystals
hydrogen bonds
solid state
catalysts
X ray diffraction

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title = "A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C5H4N-2-CH3C=N-(CH2)3NH2]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke!",
abstract = "{\circledC} 2015 Elsevier B.V. All rights reserved. The facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N1-(1-(pyridin-2-yl)ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species [Pd(L1)Cl][BF4] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a κ3-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki-Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks.",
author = "Pioquinto-Mendoza, {J. Roberto} and Patricia Conelly-Espinosa and Reyna Reyes-Mart{\'i}nez and Toscano, {Rub{\'e}n A.} and Germ{\'a}n-Acacio, {Juan M.} and Alcives Avila-Sorrosa and Oscar Baldovino-Pantale{\'o}n and David Morales-Morales",
year = "2015",
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T1 - A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C5H4N-2-CH3C=N-(CH2)3NH2]. Structural characterization and catalytic evaluation in Suzuki-Miyaura C-C couplings Dedicated with great admiration to my friend Prof. F. Ekkehardt Hahn on the Occasion of His 60th Birthday. Happy Birthday Ekke!

AU - Pioquinto-Mendoza, J. Roberto

AU - Conelly-Espinosa, Patricia

AU - Reyes-Martínez, Reyna

AU - Toscano, Rubén A.

AU - Germán-Acacio, Juan M.

AU - Avila-Sorrosa, Alcives

AU - Baldovino-Pantaleón, Oscar

AU - Morales-Morales, David

PY - 2015/11/15

Y1 - 2015/11/15

N2 - © 2015 Elsevier B.V. All rights reserved. The facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N1-(1-(pyridin-2-yl)ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species [Pd(L1)Cl][BF4] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a κ3-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki-Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks.

AB - © 2015 Elsevier B.V. All rights reserved. The facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N1-(1-(pyridin-2-yl)ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species [Pd(L1)Cl][BF4] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a κ3-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki-Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks.

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