Resumen
A xanthate-based oxidative radical process for the direct alkylation of the coumarin ring system is presented. In the reaction, a vinylic and unactivated C–H bond of the coumarin system is replaced by an α-acyl functionality under neutral conditions. This reaction has a high reaction site selectivity, which can realize alkylation at the C-3 position.
Idioma original | Inglés |
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Páginas (desde-hasta) | 4098-4101 |
Número de páginas | 4 |
Publicación | European Journal of Organic Chemistry |
Volumen | 2015 |
N.º | 19 |
DOI | |
Estado | Publicada - jul. 2015 |