Van't Huff's equation for endoreversible chemical reactions

F. Angulo-Brown; L. A. Arias-Hernândez

doi:10.1021/jp953017q

Van't Huff's equation for endoreversible chemical reactions

F. Angulo-Brown, L. A. Arias-Hernândez

Escuela Superior de Física y Matemáticas (ESFM)

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

We propose that the so-called van't Hoff s equation for the enthalpy changes in a chemical reaction may be modified in the context of endoreversible thermodynamics. This modification takes into account the role played by the heat supplied by the thermal bath for maintaining constant the temperature of the chemical system. We analyze the reaction of hydrogen iodide synthesis by means of the modified van't Hoff s equation.

Original language	English
Pages (from-to)	9193-9195
Number of pages	3
Journal	Journal of physical chemistry
Volume	100
Issue number	21
DOIs	https://doi.org/10.1021/jp953017q
State	Published - 1996

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abstract = "We propose that the so-called van't Hoff s equation for the enthalpy changes in a chemical reaction may be modified in the context of endoreversible thermodynamics. This modification takes into account the role played by the heat supplied by the thermal bath for maintaining constant the temperature of the chemical system. We analyze the reaction of hydrogen iodide synthesis by means of the modified van't Hoff s equation.",

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AU - Arias-Hernândez, L. A.

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N2 - We propose that the so-called van't Hoff s equation for the enthalpy changes in a chemical reaction may be modified in the context of endoreversible thermodynamics. This modification takes into account the role played by the heat supplied by the thermal bath for maintaining constant the temperature of the chemical system. We analyze the reaction of hydrogen iodide synthesis by means of the modified van't Hoff s equation.

AB - We propose that the so-called van't Hoff s equation for the enthalpy changes in a chemical reaction may be modified in the context of endoreversible thermodynamics. This modification takes into account the role played by the heat supplied by the thermal bath for maintaining constant the temperature of the chemical system. We analyze the reaction of hydrogen iodide synthesis by means of the modified van't Hoff s equation.

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U2 - 10.1021/jp953017q

DO - 10.1021/jp953017q

M3 - Artículo

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VL - 100

SP - 9193

EP - 9195

JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 21

ER -

Van't Huff's equation for endoreversible chemical reactions

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