Triangulo-μ<inf>3</inf>-sulfido-trinickel(II) cone-shaped clusters and anion traps: Structural characterization

Horacio López-Sandoval, Arlette Richaud, Rosalinda Contreras, G. Jeffery Leigh, Peter B. Hitchcock, Angelina Flores-Parra, Juan Carlos Galvez-Ruíz, Alejandro Cruz, Heinrich Nöth, Noráh Barba-Behrens

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Trinuclear Ni3S4N3 clusters were obtained from (1S,2S)-1-monothiasulfato-1-phenyl-2-(methylammoniumyl)propane (tpmp). Three homochiral ligand molecules together with three NiII ions give rise to a cone-shaped cluster topped by a μ3-sulfide ion. Each NiII is in a distorted planar geometry. X-ray structural studies showed that in three cases the three phenyl groups form the rim of a cage which contains R-OSO3 (R=C2H5, C3H 7) or nitrate anions. The alkyl sulfates were generated during the synthesis reaction, and are hydrogen-bonded through the oxygen atoms to the amine nitrogen atoms. The corresponding compound with the methyl sulfate anion (MeOSO3) reacts with FeIII nitrate to form a similar compound in which the nitrate anion occupies the cavity and its crystals were analyzed by X-ray diffraction. © 2004 Elsevier Ltd. All rights reserved.
Original languageAmerican English
Pages (from-to)1837-1843
Number of pages1652
StatePublished - 17 Jun 2004
Externally publishedYes


Cite this

López-Sandoval, H., Richaud, A., Contreras, R., Leigh, G. J., Hitchcock, P. B., Flores-Parra, A., Galvez-Ruíz, J. C., Cruz, A., Nöth, H., & Barba-Behrens, N. (2004). Triangulo-μ<inf>3</inf>-sulfido-trinickel(II) cone-shaped clusters and anion traps: Structural characterization. Polyhedron, 1837-1843.