TY - JOUR
T1 - Synthesis of zeolite LTA using an agro-industrial residue as the SiO 2 precursor and evaluating its effectiveness in the removal of copper ions from water
AU - González-Rodríguez, Luis Mario
AU - Pérez-Durán, Nicolás Alán
AU - Loredo-Cancino, Margarita
AU - Flores-Escamilla, Gerardo Antonio
AU - De Haro-Del Río, David Alejandro
N1 - Publisher Copyright:
© 2019 Desalination Publications. All rights reserved.
PY - 2019/3
Y1 - 2019/3
N2 - This paper deals with the synthesis and characterization of zeolite type A (ZA) using an agro-industrial residue such as barley husk as ecological and nonexpensive silica (SiO 2 ) precursor. The amorphous silica phase was achieved by pyrolysis and then was used to form a synthetic gel in a typical hydrothermal procedure where the carbonaceous phase was removed by calcination afterwards. The characterization of prepared materials by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy techniques was carried out. ZA was evaluated in the removal of copper ions from water by atomic absorption spectrophotometry. Also, kinetic studies by using pseudo-first-order (PFO) and pseudo-second-order models were carried out to evaluate the performance of ZA. The PFO model showed a better approximation for ZA data. Finally, thermodynamic equilibrium was well represented by Langmuir and Freundlich models achieving a maximum adsorption capacity of 143.9 mg g –1 .
AB - This paper deals with the synthesis and characterization of zeolite type A (ZA) using an agro-industrial residue such as barley husk as ecological and nonexpensive silica (SiO 2 ) precursor. The amorphous silica phase was achieved by pyrolysis and then was used to form a synthetic gel in a typical hydrothermal procedure where the carbonaceous phase was removed by calcination afterwards. The characterization of prepared materials by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy techniques was carried out. ZA was evaluated in the removal of copper ions from water by atomic absorption spectrophotometry. Also, kinetic studies by using pseudo-first-order (PFO) and pseudo-second-order models were carried out to evaluate the performance of ZA. The PFO model showed a better approximation for ZA data. Finally, thermodynamic equilibrium was well represented by Langmuir and Freundlich models achieving a maximum adsorption capacity of 143.9 mg g –1 .
KW - Barley husk ash
KW - Copper adsorption
KW - Kinetic models
KW - Revalorization
KW - Zeolite LTA
UR - http://www.scopus.com/inward/record.url?scp=85062833416&partnerID=8YFLogxK
U2 - 10.5004/dwt.2019.23535
DO - 10.5004/dwt.2019.23535
M3 - Artículo
SN - 1944-3994
VL - 144
SP - 156
EP - 165
JO - Desalination and Water Treatment
JF - Desalination and Water Treatment
ER -