TY - JOUR
T1 - Synthesis of polyhydroxylated Δ13-17,17-dialkyl-18- norsteroids by BF3·Et2O/Ac2O-promoted Wagner-Meerwein rearrangement of furostanols
AU - Iglesias-Arteaga, Martín A.
AU - Mendez-Stivalet, José M.
AU - Pérez, Nury
PY - 2007
Y1 - 2007
N2 - Two polyhydroxylated Δ13-17,17-dialkyl-18-norsteroids were prepared by BF3·Et2O/Ac2O-promoted regioselective E-ring cleavage/ 1-2 hydride shift/ Wagner-Meerwein rearrangement of furostanols derived from the steroid sapogenins diosgenin and sarsasapogenin. Details of the spectroscopic characterization are discussed. (Grapg Presented).
AB - Two polyhydroxylated Δ13-17,17-dialkyl-18-norsteroids were prepared by BF3·Et2O/Ac2O-promoted regioselective E-ring cleavage/ 1-2 hydride shift/ Wagner-Meerwein rearrangement of furostanols derived from the steroid sapogenins diosgenin and sarsasapogenin. Details of the spectroscopic characterization are discussed. (Grapg Presented).
KW - 1-2 hydride shift
KW - Furostanols
KW - NMR
KW - Tetrahydrofuran cleavage
KW - Wagner-Meerwein rearrangement
UR - http://www.scopus.com/inward/record.url?scp=55949108025&partnerID=8YFLogxK
U2 - 10.1177/1934578x0700200109
DO - 10.1177/1934578x0700200109
M3 - Artículo
SN - 1934-578X
VL - 2
SP - 47
EP - 50
JO - Natural Product Communications
JF - Natural Product Communications
IS - 1
ER -