Synthesis of neutral and cationic NHC-Au complexes as nanoparticle precursors

Diego Alberto Lomelí-Rosales; Alejandro Aguilar-Alcaraz; José Guadalupe Alvarado-Rodríguez; Elvia Becerra-Martínez; Adalberto Zamudio-Ojeda; Gilberto Velázquez-Juárez; Irma Idalia Rangel-Salas; Alejandro Aarón Peregrina-Lucano; Morelia E. López-Reyes; Sara A. Cortés-Llamas

doi:10.1016/j.poly.2020.114476

Synthesis of neutral and cationic NHC-Au complexes as nanoparticle precursors

Diego Alberto Lomelí-Rosales, Alejandro Aguilar-Alcaraz, José Guadalupe Alvarado-Rodríguez, Elvia Becerra-Martínez, Adalberto Zamudio-Ojeda, Gilberto Velázquez-Juárez, Irma Idalia Rangel-Salas, Alejandro Aarón Peregrina-Lucano, Morelia E. López-Reyes, Sara A. Cortés-Llamas

Centro de Nanociencias y Micro y Nanotecnologías (CNMN)

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The synthesis of organometallic gold complexes with symmetric N-heterocyclic carbene ligand (NHC) derivatives derived from 2-(methylthio)aniline is reported. These complexes were obtained as either molecular monocarbene complexes [Au(NHC)Cl], [Au(NHC)Cl₃], and [Au(NHC)Br₃]) or cationic biscarbene complex [Au(NHC)₂]PF₆. These compounds were tested as gold nanoparticle precursors that were stabilized by the corresponding NHC ligand.

Original language	English
Article number	114476
Journal	Polyhedron
Volume	182
DOIs	https://doi.org/10.1016/j.poly.2020.114476
State	Published - 15 May 2020

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Lomelí-Rosales, D. A., Aguilar-Alcaraz, A., Alvarado-Rodríguez, J. G., Becerra-Martínez, E., Zamudio-Ojeda, A., Velázquez-Juárez, G., Rangel-Salas, I. I., Peregrina-Lucano, A. A., López-Reyes, M. E., & Cortés-Llamas, S. A. (2020). Synthesis of neutral and cationic NHC-Au complexes as nanoparticle precursors. Polyhedron, 182, Article 114476. https://doi.org/10.1016/j.poly.2020.114476

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title = "Synthesis of neutral and cationic NHC-Au complexes as nanoparticle precursors",

abstract = "The synthesis of organometallic gold complexes with symmetric N-heterocyclic carbene ligand (NHC) derivatives derived from 2-(methylthio)aniline is reported. These complexes were obtained as either molecular monocarbene complexes [Au(NHC)Cl], [Au(NHC)Cl3], and [Au(NHC)Br3]) or cationic biscarbene complex [Au(NHC)2]PF6. These compounds were tested as gold nanoparticle precursors that were stabilized by the corresponding NHC ligand.",

author = "Lomel{\'i}-Rosales, {Diego Alberto} and Alejandro Aguilar-Alcaraz and Alvarado-Rodr{\'i}guez, {Jos{\'e} Guadalupe} and Elvia Becerra-Mart{\'i}nez and Adalberto Zamudio-Ojeda and Gilberto Vel{\'a}zquez-Ju{\'a}rez and Rangel-Salas, {Irma Idalia} and Peregrina-Lucano, {Alejandro Aar{\'o}n} and L{\'o}pez-Reyes, {Morelia E.} and Cort{\'e}s-Llamas, {Sara A.}",

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year = "2020",

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doi = "10.1016/j.poly.2020.114476",

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T1 - Synthesis of neutral and cationic NHC-Au complexes as nanoparticle precursors

AU - Lomelí-Rosales, Diego Alberto

AU - Aguilar-Alcaraz, Alejandro

AU - Alvarado-Rodríguez, José Guadalupe

AU - Becerra-Martínez, Elvia

AU - Zamudio-Ojeda, Adalberto

AU - Velázquez-Juárez, Gilberto

AU - Rangel-Salas, Irma Idalia

AU - Peregrina-Lucano, Alejandro Aarón

AU - López-Reyes, Morelia E.

AU - Cortés-Llamas, Sara A.

PY - 2020/5/15

Y1 - 2020/5/15

N2 - The synthesis of organometallic gold complexes with symmetric N-heterocyclic carbene ligand (NHC) derivatives derived from 2-(methylthio)aniline is reported. These complexes were obtained as either molecular monocarbene complexes [Au(NHC)Cl], [Au(NHC)Cl3], and [Au(NHC)Br3]) or cationic biscarbene complex [Au(NHC)2]PF6. These compounds were tested as gold nanoparticle precursors that were stabilized by the corresponding NHC ligand.

AB - The synthesis of organometallic gold complexes with symmetric N-heterocyclic carbene ligand (NHC) derivatives derived from 2-(methylthio)aniline is reported. These complexes were obtained as either molecular monocarbene complexes [Au(NHC)Cl], [Au(NHC)Cl3], and [Au(NHC)Br3]) or cationic biscarbene complex [Au(NHC)2]PF6. These compounds were tested as gold nanoparticle precursors that were stabilized by the corresponding NHC ligand.

UR - http://www.scopus.com/inward/record.url?scp=85081649421&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2020.114476

DO - 10.1016/j.poly.2020.114476

M3 - Artículo

AN - SCOPUS:85081649421

SN - 0277-5387

VL - 182

JO - Polyhedron

JF - Polyhedron

M1 - 114476

ER -

Synthesis of neutral and cationic NHC-Au complexes as nanoparticle precursors

Abstract

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