Synthesis and Structural Characterization of BaTiO3 Doped with Gd3+

J. P. Hernández-Lara; M. Pérez-Labra; F. R. Barrientos-Hernández; J. A. Romero-Serrano; A. Hernández-Ramírez; A. Arenas-Flores; Pandiyan Thangarasu

doi:10.1007/978-3-319-51382-9_88

Synthesis and Structural Characterization of BaTiO₃ Doped with Gd³⁺

J. P. Hernández-Lara, M. Pérez-Labra, F. R. Barrientos-Hernández, J. A. Romero-Serrano, A. Hernández-Ramírez, A. Arenas-Flores, Pandiyan Thangarasu

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

BaTiO₃ doped with Gd³⁺, was synthesized from BaCO₃, TiO₂, and Gd₂O₃ as powders using the solid state reaction method (Ba_1-xGd_xTi_1-x/4O₃). The milling of the precursors was performed in an agate mortar with acetone as control means and compositions x=0.001, 0.005, 0.05, 0.15, 0.25, 0.35 Gd³⁺ (wt%). Firstly, the powder mixture was decarbonated at 900°C for 8h, after it was sintered at 1400°C for 5h. Tetragonality of synthesized BaTiO₃ doped with Gd³⁺ was analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Raman spectroscopy (RS). Subsequently, the powders sintered were uniaxially compacted cold until to obtain pellets of about 10mm in diameter; which again were sintered at 1400°C for 4h. XRD patterns and Raman spectra results revealed that the crystal phase of the obtained particles was predominately tetragonal BaTiO₃.

Original language	English
Title of host publication	Characterization of Minerals, Metals, and Materials 2017
Editors	Jian Li, Sergio Neves Monteiro, Juan P. Escobedo-Diaz, Jeongguk Kim, Ramasis Goswami, Jiann-Yang Hwang, Yunus Eren Kalay, Bowen Li, Mingming Zhang, Shadia Ikhmayies, John S. Carpenter, Zhiwei Peng, Donato Firrao, Chenguang Bai
Publisher	Springer International Publishing
Pages	809-814
Number of pages	6
ISBN (Print)	9783319513812
DOIs	https://doi.org/10.1007/978-3-319-51382-9_88
State	Published - 2017
Externally published	Yes
Event	International Symposium on Characterization of Minerals, Metals, and Materials, 2017 - San Diego, United States Duration: 26 Feb 2017 → 2 Mar 2017

Publication series

Name	Minerals, Metals and Materials Series
Volume	Part F7
ISSN (Print)	2367-1181
ISSN (Electronic)	2367-1696

Conference

Conference	International Symposium on Characterization of Minerals, Metals, and Materials, 2017
Country/Territory	United States
City	San Diego
Period	26/02/17 → 2/03/17

Keywords

Batio
Ceramics
Doping
Ferroelectrics
Tetragonality

Access to Document

10.1007/978-3-319-51382-9_88

Cite this

Hernández-Lara, J. P., Pérez-Labra, M., Barrientos-Hernández, F. R., Romero-Serrano, J. A., Hernández-Ramírez, A., Arenas-Flores, A., & Thangarasu, P. (2017). Synthesis and Structural Characterization of BaTiO₃ Doped with Gd³⁺. In J. Li, S. N. Monteiro, J. P. Escobedo-Diaz, J. Kim, R. Goswami, J.-Y. Hwang, Y. E. Kalay, B. Li, M. Zhang, S. Ikhmayies, J. S. Carpenter, Z. Peng, D. Firrao, & C. Bai (Eds.), Characterization of Minerals, Metals, and Materials 2017 (pp. 809-814). (Minerals, Metals and Materials Series; Vol. Part F7). Springer International Publishing. https://doi.org/10.1007/978-3-319-51382-9_88

Hernández-Lara, J. P. ; Pérez-Labra, M. ; Barrientos-Hernández, F. R. et al. / Synthesis and Structural Characterization of BaTiO₃ Doped with Gd³⁺. Characterization of Minerals, Metals, and Materials 2017. editor / Jian Li ; Sergio Neves Monteiro ; Juan P. Escobedo-Diaz ; Jeongguk Kim ; Ramasis Goswami ; Jiann-Yang Hwang ; Yunus Eren Kalay ; Bowen Li ; Mingming Zhang ; Shadia Ikhmayies ; John S. Carpenter ; Zhiwei Peng ; Donato Firrao ; Chenguang Bai. Springer International Publishing, 2017. pp. 809-814 (Minerals, Metals and Materials Series).

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title = "Synthesis and Structural Characterization of BaTiO3 Doped with Gd3+",

abstract = "BaTiO3 doped with Gd3+, was synthesized from BaCO3, TiO2, and Gd2O3 as powders using the solid state reaction method (Ba1-xGdxTi1-x/4O3). The milling of the precursors was performed in an agate mortar with acetone as control means and compositions x=0.001, 0.005, 0.05, 0.15, 0.25, 0.35 Gd3+ (wt%). Firstly, the powder mixture was decarbonated at 900°C for 8h, after it was sintered at 1400°C for 5h. Tetragonality of synthesized BaTiO3 doped with Gd3+ was analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Raman spectroscopy (RS). Subsequently, the powders sintered were uniaxially compacted cold until to obtain pellets of about 10mm in diameter; which again were sintered at 1400°C for 4h. XRD patterns and Raman spectra results revealed that the crystal phase of the obtained particles was predominately tetragonal BaTiO3.",

keywords = "Batio, Ceramics, Doping, Ferroelectrics, Tetragonality",

author = "Hern{\'a}ndez-Lara, {J. P.} and M. P{\'e}rez-Labra and Barrientos-Hern{\'a}ndez, {F. R.} and Romero-Serrano, {J. A.} and A. Hern{\'a}ndez-Ram{\'i}rez and A. Arenas-Flores and Pandiyan Thangarasu",

note = "Publisher Copyright: {\textcopyright} The Minerals, Metals & Materials Society 2017.; International Symposium on Characterization of Minerals, Metals, and Materials, 2017 ; Conference date: 26-02-2017 Through 02-03-2017",

year = "2017",

doi = "10.1007/978-3-319-51382-9_88",

language = "Ingl{\'e}s",

isbn = "9783319513812",

series = "Minerals, Metals and Materials Series",

publisher = "Springer International Publishing",

pages = "809--814",

editor = "Jian Li and Monteiro, {Sergio Neves} and Escobedo-Diaz, {Juan P.} and Jeongguk Kim and Ramasis Goswami and Jiann-Yang Hwang and Kalay, {Yunus Eren} and Bowen Li and Mingming Zhang and Shadia Ikhmayies and Carpenter, {John S.} and Zhiwei Peng and Donato Firrao and Chenguang Bai",

booktitle = "Characterization of Minerals, Metals, and Materials 2017",

}

Hernández-Lara, JP, Pérez-Labra, M, Barrientos-Hernández, FR, Romero-Serrano, JA , Hernández-Ramírez, A, Arenas-Flores, A & Thangarasu, P 2017, Synthesis and Structural Characterization of BaTiO₃ Doped with Gd³⁺. in J Li, SN Monteiro, JP Escobedo-Diaz, J Kim, R Goswami, J-Y Hwang, YE Kalay, B Li, M Zhang, S Ikhmayies, JS Carpenter, Z Peng, D Firrao & C Bai (eds), Characterization of Minerals, Metals, and Materials 2017. Minerals, Metals and Materials Series, vol. Part F7, Springer International Publishing, pp. 809-814, International Symposium on Characterization of Minerals, Metals, and Materials, 2017, San Diego, United States, 26/02/17. https://doi.org/10.1007/978-3-319-51382-9_88

Synthesis and Structural Characterization of BaTiO₃ Doped with Gd³⁺. / Hernández-Lara, J. P.; Pérez-Labra, M.; Barrientos-Hernández, F. R. et al.
Characterization of Minerals, Metals, and Materials 2017. ed. / Jian Li; Sergio Neves Monteiro; Juan P. Escobedo-Diaz; Jeongguk Kim; Ramasis Goswami; Jiann-Yang Hwang; Yunus Eren Kalay; Bowen Li; Mingming Zhang; Shadia Ikhmayies; John S. Carpenter; Zhiwei Peng; Donato Firrao; Chenguang Bai. Springer International Publishing, 2017. p. 809-814 (Minerals, Metals and Materials Series; Vol. Part F7).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Synthesis and Structural Characterization of BaTiO3 Doped with Gd3+

AU - Hernández-Lara, J. P.

AU - Pérez-Labra, M.

AU - Barrientos-Hernández, F. R.

AU - Romero-Serrano, J. A.

AU - Hernández-Ramírez, A.

AU - Arenas-Flores, A.

AU - Thangarasu, Pandiyan

N1 - Publisher Copyright: © The Minerals, Metals & Materials Society 2017.

PY - 2017

Y1 - 2017

N2 - BaTiO3 doped with Gd3+, was synthesized from BaCO3, TiO2, and Gd2O3 as powders using the solid state reaction method (Ba1-xGdxTi1-x/4O3). The milling of the precursors was performed in an agate mortar with acetone as control means and compositions x=0.001, 0.005, 0.05, 0.15, 0.25, 0.35 Gd3+ (wt%). Firstly, the powder mixture was decarbonated at 900°C for 8h, after it was sintered at 1400°C for 5h. Tetragonality of synthesized BaTiO3 doped with Gd3+ was analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Raman spectroscopy (RS). Subsequently, the powders sintered were uniaxially compacted cold until to obtain pellets of about 10mm in diameter; which again were sintered at 1400°C for 4h. XRD patterns and Raman spectra results revealed that the crystal phase of the obtained particles was predominately tetragonal BaTiO3.

AB - BaTiO3 doped with Gd3+, was synthesized from BaCO3, TiO2, and Gd2O3 as powders using the solid state reaction method (Ba1-xGdxTi1-x/4O3). The milling of the precursors was performed in an agate mortar with acetone as control means and compositions x=0.001, 0.005, 0.05, 0.15, 0.25, 0.35 Gd3+ (wt%). Firstly, the powder mixture was decarbonated at 900°C for 8h, after it was sintered at 1400°C for 5h. Tetragonality of synthesized BaTiO3 doped with Gd3+ was analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Raman spectroscopy (RS). Subsequently, the powders sintered were uniaxially compacted cold until to obtain pellets of about 10mm in diameter; which again were sintered at 1400°C for 4h. XRD patterns and Raman spectra results revealed that the crystal phase of the obtained particles was predominately tetragonal BaTiO3.

KW - Batio

KW - Ceramics

KW - Doping

KW - Ferroelectrics

KW - Tetragonality

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U2 - 10.1007/978-3-319-51382-9_88

DO - 10.1007/978-3-319-51382-9_88

M3 - Contribución a la conferencia

SN - 9783319513812

T3 - Minerals, Metals and Materials Series

SP - 809

EP - 814

BT - Characterization of Minerals, Metals, and Materials 2017

A2 - Li, Jian

A2 - Monteiro, Sergio Neves

A2 - Escobedo-Diaz, Juan P.

A2 - Kim, Jeongguk

A2 - Goswami, Ramasis

A2 - Hwang, Jiann-Yang

A2 - Kalay, Yunus Eren

A2 - Li, Bowen

A2 - Zhang, Mingming

A2 - Ikhmayies, Shadia

A2 - Carpenter, John S.

A2 - Peng, Zhiwei

A2 - Firrao, Donato

A2 - Bai, Chenguang

PB - Springer International Publishing

T2 - International Symposium on Characterization of Minerals, Metals, and Materials, 2017

Y2 - 26 February 2017 through 2 March 2017

ER -

Hernández-Lara JP, Pérez-Labra M, Barrientos-Hernández FR, Romero-Serrano JA , Hernández-Ramírez A, Arenas-Flores A et al. Synthesis and Structural Characterization of BaTiO₃ Doped with Gd³⁺. In Li J, Monteiro SN, Escobedo-Diaz JP, Kim J, Goswami R, Hwang JY, Kalay YE, Li B, Zhang M, Ikhmayies S, Carpenter JS, Peng Z, Firrao D, Bai C, editors, Characterization of Minerals, Metals, and Materials 2017. Springer International Publishing. 2017. p. 809-814. (Minerals, Metals and Materials Series). doi: 10.1007/978-3-319-51382-9_88