TY - JOUR
T1 - Synthesis and characterization of three new di-n-butyl [bis (Alkyl-aminopropionic acid)]tin (iv)
AU - Nieto-Alvarez, David Aaron
AU - Zamudio-Rivera, Luis S.
AU - Hernández-Altamirano, Raúl
AU - Mena-Cervantes, Violeta Y.
AU - Barba, Victor
AU - Flores-Sandoval, César
N1 - Publisher Copyright:
© 2016, Sociedad Química de México.
PY - 2016
Y1 - 2016
N2 - The synthesis of novel di-n-butyl [bis (alkyl-aminopropion-ic acid)]tin (IV) (alkyl = octyl, dodecyl, octadecyl) 2a-2c is reported. The complexes were characterized by1H,13C,119Sn NMR, IR, MS and elemental analyses. For compound 2a the119Sn NMR showed the presence of five signals suggesting the existence of a mixture of five hexa–coordinated species in equilibrium, two trans (I, II) and three cis (III, IV, V). In contrast, the compounds 2b and 2c present only unique hexa–coordinated specie.
AB - The synthesis of novel di-n-butyl [bis (alkyl-aminopropion-ic acid)]tin (IV) (alkyl = octyl, dodecyl, octadecyl) 2a-2c is reported. The complexes were characterized by1H,13C,119Sn NMR, IR, MS and elemental analyses. For compound 2a the119Sn NMR showed the presence of five signals suggesting the existence of a mixture of five hexa–coordinated species in equilibrium, two trans (I, II) and three cis (III, IV, V). In contrast, the compounds 2b and 2c present only unique hexa–coordinated specie.
KW - Diorganotin
KW - Organotin
KW - Sn (IV) complex
KW - Spectros copy
KW - Tin
UR - http://www.scopus.com/inward/record.url?scp=85014735711&partnerID=8YFLogxK
M3 - Artículo
SN - 1870-249X
VL - 60
SP - 194
EP - 199
JO - Journal of the Mexican Chemical Society
JF - Journal of the Mexican Chemical Society
IS - 4
ER -