Study of the nature of the interaction of CH3CN with Lewis acids

José Fernández Bertrán, Edilso Reguera Ruíz

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

The unperturbed ν 0 (CN) stretching frequencies of CH 3 CN in 18 complexes with Lewis acids are correlated with ν (CN) frequencies in cobalticyanides and with cation parameters which measure σ and π interactions. The results indicate that the nature of the interaction is predominantly of the σ donor-acceptor type wib no detectable π back-donation from the cation to the CN ligand. © 1992.
Original languageAmerican English
Pages (from-to)43-46
Number of pages4
JournalSpectrochimica Acta Part A: Molecular Spectroscopy
DOIs
StatePublished - 1 Jan 1993
Externally publishedYes

Fingerprint Dive into the research topics of 'Study of the nature of the interaction of CH3CN with Lewis acids'. Together they form a unique fingerprint.

  • Cite this