Structural characterization of microcrystalline-amorphous hydrogenated silicon samples prepared by PECVD method

A. Orduña-Díaz, M. Rojas-López, V. L. Gayou, R. Delgado-Macuil, V. H. Méndez-García, R. E. Pérez-Blanco, E. Rosendo

Research output: Contribution to journalConference articlepeer-review

Abstract

Microcrystalline-amorphous doped hydrogenated silicon (μc n+ a-Si:H) samples were prepared by using plasma enhanced chemical vapor deposition (PECVD) method. The samples were deposited on coming substrates at 270°C and then were annealed at 250°C during several hours. Raman scattering spectroscopy was employed to study the amorphous-microcrystalline (μc/a) phase transition and the subsequent microcrystallization process as a function of the annealing time. It was found that the conductivity of the material is closely related to the normalized Raman intensity of the LO mode. In this work, such relation is explained in terms of the impurities activation and by the hydrogen effusion, which takes place during the annealing process. Samples morphology was characterized by atomic force microscopy (AFM). Crystallized silicon islands were observed with an average diameter depending on the annealing time.

Original languageEnglish
Article number289
Pages (from-to)1540-1543
Number of pages4
JournalProceedings of SPIE - The International Society for Optical Engineering
Volume5622
Issue numberPART 3
DOIs
StatePublished - 2004
EventRIAO/OPTILAS 2004: 5th Iberoamerican Meeting on Optics, and 8th Latin American Meeting on Optics, Lasers, and their Applications; ICO Regional Meeting - Porlamar, Venezuela, Bolivarian Republic of
Duration: 3 Oct 20048 Oct 2004

Keywords

  • Amorphous silicon
  • Atomic force microscopy
  • PECVD
  • Raman scattering

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