Silver removal from molten lead through zinc powder injection

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Abstract

A silver removal process was carried out on a Pb-Ag alloy through zinc powder injection of three different sizes (3.55, 44.4 and 734.8 μm) with a top submerged lance using nitrogen as carrying gas. The higher silver removal was obtained for the zinc powder size of 44.4 μm, while the lowest silver removal efficiency was attained for the smaller particle size. The AgZn phase was detected in the slag for the 44.4 and 734.8 μm particle sizes by XRD, which was in agreement with SEM-EDS analysis. Experimental behavior was explained according to the melting and residence time of the injected particles.

Original languageEnglish
Pages (from-to)544-552
Number of pages9
JournalTransactions of Nonferrous Metals Society of China (English Edition)
Volume24
Issue number2
DOIs
StatePublished - Feb 2014
Externally publishedYes

Keywords

  • desilvering ratio
  • lead
  • particle size
  • powder injection
  • residence time
  • silver

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