Role of the water of crystallization in the Mössbauer spectra of some low-spin ferric and high-spin ferrous compounds. Its implications in comparative studies

E. Reguera; J. Fernández-Bertrán

doi:10.1007/BF02162885

Role of the water of crystallization in the Mössbauer spectra of some low-spin ferric and high-spin ferrous compounds. Its implications in comparative studies

E. Reguera, J. Fernández-Bertrán

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Abstract

Mössbauer spectra of low-spin ferric and high-spin ferrous compounds may be sensitive to the local humidity during the measuring process or to other parameters associated with the hydration degree of the sample. This effect is related to the location of water molecules around the t_2g orbitals (d_xy, d_xz, d_yz). The results indicate that for comparative studies all Mössbauer measurements must be carried out in well standardized conditions.

Original language	English
Pages (from-to)	443-455
Number of pages	13
Journal	Journal of Radioanalytical and Nuclear Chemistry Letters
Volume	200
Issue number	5
DOIs	https://doi.org/10.1007/BF02162885
State	Published - Jul 1995
Externally published	Yes

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abstract = "M{\"o}ssbauer spectra of low-spin ferric and high-spin ferrous compounds may be sensitive to the local humidity during the measuring process or to other parameters associated with the hydration degree of the sample. This effect is related to the location of water molecules around the t2g orbitals (dxy, dxz, dyz). The results indicate that for comparative studies all M{\"o}ssbauer measurements must be carried out in well standardized conditions.",

author = "E. Reguera and J. Fern{\'a}ndez-Bertr{\'a}n",

year = "1995",

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AU - Reguera, E.

AU - Fernández-Bertrán, J.

PY - 1995/7

Y1 - 1995/7

N2 - Mössbauer spectra of low-spin ferric and high-spin ferrous compounds may be sensitive to the local humidity during the measuring process or to other parameters associated with the hydration degree of the sample. This effect is related to the location of water molecules around the t2g orbitals (dxy, dxz, dyz). The results indicate that for comparative studies all Mössbauer measurements must be carried out in well standardized conditions.

AB - Mössbauer spectra of low-spin ferric and high-spin ferrous compounds may be sensitive to the local humidity during the measuring process or to other parameters associated with the hydration degree of the sample. This effect is related to the location of water molecules around the t2g orbitals (dxy, dxz, dyz). The results indicate that for comparative studies all Mössbauer measurements must be carried out in well standardized conditions.

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DO - 10.1007/BF02162885

M3 - Artículo

SN - 0236-5731

VL - 200

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EP - 455

JO - Journal of Radioanalytical and Nuclear Chemistry Letters

JF - Journal of Radioanalytical and Nuclear Chemistry Letters

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ER -

Role of the water of crystallization in the Mössbauer spectra of some low-spin ferric and high-spin ferrous compounds. Its implications in comparative studies

Abstract

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