TY - JOUR
T1 - Reactivity of iridium(I) complexes containing the bis(diphenylthiophosphinoyl)-1,2,3-triazolate ligand toward bis(diphenylphosphino)ethane
AU - Solís-Huitrón, Josué
AU - Hernández-Juárez, Martín
AU - Martínez-Otero, Diego
AU - Zúñiga-Villarreal, Noé
N1 - Publisher Copyright:
© 2019
PY - 2019/5/1
Y1 - 2019/5/1
N2 - The complexes [Ir(dppe)2][S,N-(4,5-(P(S)Ph2)2Tz] (2) and [Ir(κ2-S,N-(4,5-(P(S)Ph2)2Tz))(dppe)] (3) were obtained as a mixture upon equimolar reaction of complex [Ir(κ2-S,N-(4,5-(P(S)Ph2)2Tz))(coe)2] (1) with bis(diphenylphosphino)ethane (dppe). Reaction protocols for the selective preparation of complexes 2 and 3 were devised. An intermediate complex 5, [Ir(κ-N-4,5-(P(S)Ph2)2Tz)(cod)(dppe)], for the formation of 2 and 3 was characterized in solution and in the solid state. Both complexes, 2 and 3, are prone to activation of molecular oxygen.
AB - The complexes [Ir(dppe)2][S,N-(4,5-(P(S)Ph2)2Tz] (2) and [Ir(κ2-S,N-(4,5-(P(S)Ph2)2Tz))(dppe)] (3) were obtained as a mixture upon equimolar reaction of complex [Ir(κ2-S,N-(4,5-(P(S)Ph2)2Tz))(coe)2] (1) with bis(diphenylphosphino)ethane (dppe). Reaction protocols for the selective preparation of complexes 2 and 3 were devised. An intermediate complex 5, [Ir(κ-N-4,5-(P(S)Ph2)2Tz)(cod)(dppe)], for the formation of 2 and 3 was characterized in solution and in the solid state. Both complexes, 2 and 3, are prone to activation of molecular oxygen.
UR - http://www.scopus.com/inward/record.url?scp=85062475009&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2019.03.007
DO - 10.1016/j.ica.2019.03.007
M3 - Artículo
AN - SCOPUS:85062475009
SN - 0020-1693
VL - 490
SP - 78
EP - 84
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
ER -