Photodegradation of phenol and cresol in aqueous medium by using Zn/Al + Fe mixed oxides obtained from layered double hydroxides materials

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Abstract

ZnAlFe layered double hydroxides (LDHs) were synthesized by the co-precipitation method at different MII/MIII ratio. The solids were calcined at 723 K obtaining the respective mixed oxides with high specific surface areas (138-70 m2/g) and semiconductor properties (band gap values of 2.54-2.04 eV). The photocatalytic activity of these materials was tested for the photodegradation of aqueous solutions containing phenol and p-cresol (40 ppm), in presence of a UV light source. A disappearance of 98% of phenol and a total photodegradation of p-cresol were obtained after 6 and 4 h, respectively.

Original languageEnglish
Pages (from-to)353-357
Number of pages5
JournalCatalysis Today
Volume150
Issue number3-4
DOIs
StatePublished - 30 Mar 2010
Externally publishedYes

Keywords

  • Energy band gap LDHs
  • LDHs co-precipitation
  • Phenol photodegradation
  • ZnAlFe layered double hydroxides
  • p-Cresol photodegradation

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