Modeling the deactivation by metal deposition of heavy oil hydrotreating catalyst

Ignacio Elizalde; Jorge Ancheyta

doi:10.1016/j.cattod.2013.04.008

Modeling the deactivation by metal deposition of heavy oil hydrotreating catalyst

Ignacio Elizalde, Jorge Ancheyta

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Modeling the deactivation of heavy oil hydrotreating catalyst was carried out by using a pore plugging model. Experimental data were obtained at constant temperature of 385 C, pressure of 9.8 MPa, LHSV of 0.25 h and 5000 scf H ₂/bbl oil. Kinetics was derived from experimental data collected at short times-on-stream (TOS) whereas data affected by pore plugging by metal deposition was obtained between 200 and 2200 h TOS. The model employed was capable of predicting with confidence the profiles of diminution of metal removal (nickel and vanadium) at short and long values of time-on-stream.

Original language	English
Pages (from-to)	221-227
Number of pages	7
Journal	Catalysis Today
Volume	220-222
DOIs	https://doi.org/10.1016/j.cattod.2013.04.008
State	Published - Mar 2014
Externally published	Yes

Keywords

Deactivation
Heavy oil
Pore plugging

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10.1016/j.cattod.2013.04.008

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title = "Modeling the deactivation by metal deposition of heavy oil hydrotreating catalyst",

abstract = "Modeling the deactivation of heavy oil hydrotreating catalyst was carried out by using a pore plugging model. Experimental data were obtained at constant temperature of 385 C, pressure of 9.8 MPa, LHSV of 0.25 h and 5000 scf H 2/bbl oil. Kinetics was derived from experimental data collected at short times-on-stream (TOS) whereas data affected by pore plugging by metal deposition was obtained between 200 and 2200 h TOS. The model employed was capable of predicting with confidence the profiles of diminution of metal removal (nickel and vanadium) at short and long values of time-on-stream.",

keywords = "Deactivation, Heavy oil, Pore plugging",

author = "Ignacio Elizalde and Jorge Ancheyta",

note = "Funding Information: I. Elizalde thanks IMP and Consejo Nacional de Ciencia y Tecnolog{\'i}a (CONACyT-M{\'e}xico) for financial support.",

year = "2014",

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doi = "10.1016/j.cattod.2013.04.008",

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volume = "220-222",

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journal = "Catalysis Today",

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TY - JOUR

T1 - Modeling the deactivation by metal deposition of heavy oil hydrotreating catalyst

AU - Elizalde, Ignacio

AU - Ancheyta, Jorge

N1 - Funding Information: I. Elizalde thanks IMP and Consejo Nacional de Ciencia y Tecnología (CONACyT-México) for financial support.

PY - 2014/3

Y1 - 2014/3

N2 - Modeling the deactivation of heavy oil hydrotreating catalyst was carried out by using a pore plugging model. Experimental data were obtained at constant temperature of 385 C, pressure of 9.8 MPa, LHSV of 0.25 h and 5000 scf H 2/bbl oil. Kinetics was derived from experimental data collected at short times-on-stream (TOS) whereas data affected by pore plugging by metal deposition was obtained between 200 and 2200 h TOS. The model employed was capable of predicting with confidence the profiles of diminution of metal removal (nickel and vanadium) at short and long values of time-on-stream.

AB - Modeling the deactivation of heavy oil hydrotreating catalyst was carried out by using a pore plugging model. Experimental data were obtained at constant temperature of 385 C, pressure of 9.8 MPa, LHSV of 0.25 h and 5000 scf H 2/bbl oil. Kinetics was derived from experimental data collected at short times-on-stream (TOS) whereas data affected by pore plugging by metal deposition was obtained between 200 and 2200 h TOS. The model employed was capable of predicting with confidence the profiles of diminution of metal removal (nickel and vanadium) at short and long values of time-on-stream.

KW - Deactivation

KW - Heavy oil

KW - Pore plugging

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U2 - 10.1016/j.cattod.2013.04.008

DO - 10.1016/j.cattod.2013.04.008

M3 - Artículo

AN - SCOPUS:84889686591

SN - 0920-5861

VL - 220-222

SP - 221

EP - 227

JO - Catalysis Today

JF - Catalysis Today

ER -

Modeling the deactivation by metal deposition of heavy oil hydrotreating catalyst

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Keywords

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