Mechanism of crystallization of oxygen-doped amorphous Ge 1Sb2Te4 thin films

C. Rivera-Rodríguez, E. Prokhorov, G. Trapaga, E. Morales-Sánchez, M. Hernandez-Landaverde, Yu Kovalenko, J. González-Hernández

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30 Scopus citations

Abstract

The mechanisms of the amorphous-to-crystalline phase transformation in Ge1Sb2Te4 alloys doped by oxygen in the range of 4-28 at.% were studied. In samples with oxygen in the range of 10-15 at.% crystallization was found to occur in two stages, producing samples where Ge1Sb2Te4 and Sb2Te3 coexist. In the samples with higher oxygen content (in the range of 15-28 at.%), the films were found to crystallize into the rombohedral Sb2Te 3 phase due to the formation of amorphous germanium oxide. Three different crystallization mechanisms for materials with different content of oxygen were proposed.

Original languageEnglish
Pages (from-to)1040-1046
Number of pages7
JournalJournal of Applied Physics
Volume96
Issue number2
DOIs
StatePublished - 15 Jul 2004
Externally publishedYes

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