TY - JOUR
T1 - Luminescence properties of aligned-electrospun fibers of poly(9-vinylcarbazole) doped with a europium (III) complex
AU - Mondragón, Margarita
AU - Arias, Eduardo
AU - Elizalde, Luis E.
AU - Castañeda, Martha E.
AU - Moggio, Ivana
N1 - Publisher Copyright:
© 2017 Elsevier B.V.
PY - 2017/12
Y1 - 2017/12
N2 - Unaligned and aligned poly(9-vinylcarbazole) (PVK)/NaEu(TTA)4 (TTA=2-thenoyltrifluoracetone) composite fibers were prepared by electrospinning, using tetrahydrofuran (THF) and 1,2-dichoroethane (DCE) as solvents. Scanning electron microscopy (SEM) measurements showed that aligned fibers were wider and thicker than unaligned fibers. Characterization by Fourier transform-infrared (FTIR) spectroscopy indicated that there were weak interactions between PVK and NaEu(TTA)4. Alignment of composite fibers promoted packing of the molecules of the Eu(III)-complex, increased the population of fully overlapping carbazoles (f-PVK) and decreased the asymmetric ratio (R) of the NaEu(TTA)4, leading to less efficient energy transfer and lower lifetimes, as determined using steady-state and dynamic fluorescence spectroscopy. Yet, shorter lifetimes as compared to NaEu(TTA)4 in powder form were found in unaligned and aligned electrospun fibers, ascribed mainly to introduction of defect states during electrospinning. Unaligned electrospun PVK fibers doped with loosen packed europium complexes preferably could be used as promising luminescence materials.
AB - Unaligned and aligned poly(9-vinylcarbazole) (PVK)/NaEu(TTA)4 (TTA=2-thenoyltrifluoracetone) composite fibers were prepared by electrospinning, using tetrahydrofuran (THF) and 1,2-dichoroethane (DCE) as solvents. Scanning electron microscopy (SEM) measurements showed that aligned fibers were wider and thicker than unaligned fibers. Characterization by Fourier transform-infrared (FTIR) spectroscopy indicated that there were weak interactions between PVK and NaEu(TTA)4. Alignment of composite fibers promoted packing of the molecules of the Eu(III)-complex, increased the population of fully overlapping carbazoles (f-PVK) and decreased the asymmetric ratio (R) of the NaEu(TTA)4, leading to less efficient energy transfer and lower lifetimes, as determined using steady-state and dynamic fluorescence spectroscopy. Yet, shorter lifetimes as compared to NaEu(TTA)4 in powder form were found in unaligned and aligned electrospun fibers, ascribed mainly to introduction of defect states during electrospinning. Unaligned electrospun PVK fibers doped with loosen packed europium complexes preferably could be used as promising luminescence materials.
KW - Aligned composite fibers
KW - Electrospinning
KW - Europium complex
KW - Fluorescence
KW - Poly(9-vinylcarbazole)
UR - http://www.scopus.com/inward/record.url?scp=85031729284&partnerID=8YFLogxK
U2 - 10.1016/j.jlumin.2017.08.013
DO - 10.1016/j.jlumin.2017.08.013
M3 - Artículo
SN - 0022-2313
VL - 192
SP - 745
EP - 751
JO - Journal of Luminescence
JF - Journal of Luminescence
ER -