Photo-induced charge transfer in molecular materials based on Prussian blue analogs: A photoacoustic study

S. Stolik; E. Reguera; S. A. Tomás; F. Sánchez-Sinencio

doi:10.1051/jp4:20051125011

Photo-induced charge transfer in molecular materials based on Prussian blue analogs: A photoacoustic study

S. Stolik, E. Reguera, S. A. Tomás, F. Sánchez-Sinencio

Research output: Contribution to journal › Conference article › peer-review

2 Scopus citations

Abstract

Photoacoustic spectra of molecular materials based on the assembling of the [Fe(CN)₆] molecular block were recorded and evaluated. An intense absorption band around 600 nm was observed for compounds where the valence of the involved metals allows charge transfer through the CN ligand (inner photo-induced redox reactions). In the absence of this transition, only the signal corresponding to d-d transitions within the metal was observed, which falls below 450 nm, This suggests that photoacoustic spectroscopy provides a fast and reliable method to explore the existence of tunable photo-induced charge transfer in molecular materials.

Original language	English
Pages (from-to)	43-46
Number of pages	4
Journal	Journal De Physique. IV : JP
Volume	125
DOIs	https://doi.org/10.1051/jp4:20051125011
State	Published - 2005
Externally published	Yes
Event	13th ICPPP International Conference on Photoacoustic and PhotothermalPhenomena - Rio de Janeiro, Brazil Duration: 5 Jul 2004 → 8 Jul 2004

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title = "Photo-induced charge transfer in molecular materials based on Prussian blue analogs: A photoacoustic study",

abstract = "Photoacoustic spectra of molecular materials based on the assembling of the [Fe(CN)6] molecular block were recorded and evaluated. An intense absorption band around 600 nm was observed for compounds where the valence of the involved metals allows charge transfer through the CN ligand (inner photo-induced redox reactions). In the absence of this transition, only the signal corresponding to d-d transitions within the metal was observed, which falls below 450 nm, This suggests that photoacoustic spectroscopy provides a fast and reliable method to explore the existence of tunable photo-induced charge transfer in molecular materials.",

author = "S. Stolik and E. Reguera and Tom{\'a}s, {S. A.} and F. S{\'a}nchez-Sinencio",

year = "2005",

doi = "10.1051/jp4:20051125011",

language = "Ingl{\'e}s",

volume = "125",

pages = "43--46",

journal = "Journal De Physique. IV : JP",

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note = "13th ICPPP International Conference on Photoacoustic and PhotothermalPhenomena ; Conference date: 05-07-2004 Through 08-07-2004",

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T1 - Photo-induced charge transfer in molecular materials based on Prussian blue analogs

T2 - 13th ICPPP International Conference on Photoacoustic and PhotothermalPhenomena

AU - Stolik, S.

AU - Reguera, E.

AU - Tomás, S. A.

AU - Sánchez-Sinencio, F.

PY - 2005

Y1 - 2005

N2 - Photoacoustic spectra of molecular materials based on the assembling of the [Fe(CN)6] molecular block were recorded and evaluated. An intense absorption band around 600 nm was observed for compounds where the valence of the involved metals allows charge transfer through the CN ligand (inner photo-induced redox reactions). In the absence of this transition, only the signal corresponding to d-d transitions within the metal was observed, which falls below 450 nm, This suggests that photoacoustic spectroscopy provides a fast and reliable method to explore the existence of tunable photo-induced charge transfer in molecular materials.

AB - Photoacoustic spectra of molecular materials based on the assembling of the [Fe(CN)6] molecular block were recorded and evaluated. An intense absorption band around 600 nm was observed for compounds where the valence of the involved metals allows charge transfer through the CN ligand (inner photo-induced redox reactions). In the absence of this transition, only the signal corresponding to d-d transitions within the metal was observed, which falls below 450 nm, This suggests that photoacoustic spectroscopy provides a fast and reliable method to explore the existence of tunable photo-induced charge transfer in molecular materials.

UR - http://www.scopus.com/inward/record.url?scp=33645059174&partnerID=8YFLogxK

U2 - 10.1051/jp4:20051125011

DO - 10.1051/jp4:20051125011

M3 - Artículo de la conferencia

AN - SCOPUS:33645059174

SN - 1155-4339

VL - 125

SP - 43

EP - 46

JO - Journal De Physique. IV : JP

JF - Journal De Physique. IV : JP

Y2 - 5 July 2004 through 8 July 2004

ER -

Photo-induced charge transfer in molecular materials based on Prussian blue analogs: A photoacoustic study

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