Influence of the architecture of Au–Ag–Pt nanoparticles on the electrocatalytic activity for hydrogen evolution reaction

A. Londono-Calderon; C. A. Campos-Roldan; R. G. González-Huerta; M. L. Hernandez-Pichardo; P. del Angel; M. J. Yacaman

doi:10.1016/j.ijhydene.2017.08.042

Influence of the architecture of Au–Ag–Pt nanoparticles on the electrocatalytic activity for hydrogen evolution reaction

A. Londono-Calderon, C. A. Campos-Roldan, R. G. González-Huerta, M. L. Hernandez-Pichardo, P. del Angel, M. J. Yacaman

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

In this work, Au–Ag–Pt and Au@AgPt yolk-shell nanoparticles were synthetized via chemical reduction and seed-mediated galvanic replacement method, in order to obtain two different architectures with the same metal content. The architecture influence on the electrocatalytic activity towards the hydrogen evolution reaction (HER) of these nanostructured materials was evaluated in acidic media. The hierarchical architecture allows a superior electrocatalytic activity towards hydrogen evolution mainly due to the synergetic effect between the exposed metals on the surface (Pt and Ag) and the higher availability of Pt allowed by the yolk-shell structure.

Original language	English
Pages (from-to)	30208-30215
Number of pages	8
Journal	International Journal of Hydrogen Energy
Volume	42
Issue number	51
DOIs	https://doi.org/10.1016/j.ijhydene.2017.08.042
State	Published - 2017
Externally published	Yes

Keywords

Au@AgPt yolk-shell nanoparticles
Au–Ag–Pt nanoparticles
Hydrogen evolution reaction (HER)

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10.1016/j.ijhydene.2017.08.042

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Londono-Calderon, A., Campos-Roldan, C. A., González-Huerta, R. G., Hernandez-Pichardo, M. L., del Angel, P., & Yacaman, M. J. (2017). Influence of the architecture of Au–Ag–Pt nanoparticles on the electrocatalytic activity for hydrogen evolution reaction. International Journal of Hydrogen Energy, 42(51), 30208-30215. https://doi.org/10.1016/j.ijhydene.2017.08.042

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title = "Influence of the architecture of Au–Ag–Pt nanoparticles on the electrocatalytic activity for hydrogen evolution reaction",

abstract = "In this work, Au–Ag–Pt and Au@AgPt yolk-shell nanoparticles were synthetized via chemical reduction and seed-mediated galvanic replacement method, in order to obtain two different architectures with the same metal content. The architecture influence on the electrocatalytic activity towards the hydrogen evolution reaction (HER) of these nanostructured materials was evaluated in acidic media. The hierarchical architecture allows a superior electrocatalytic activity towards hydrogen evolution mainly due to the synergetic effect between the exposed metals on the surface (Pt and Ag) and the higher availability of Pt allowed by the yolk-shell structure.",

keywords = "Au@AgPt yolk-shell nanoparticles, Au–Ag–Pt nanoparticles, Hydrogen evolution reaction (HER)",

author = "A. Londono-Calderon and Campos-Roldan, {C. A.} and Gonz{\'a}lez-Huerta, {R. G.} and Hernandez-Pichardo, {M. L.} and {del Angel}, P. and Yacaman, {M. J.}",

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year = "2017",

doi = "10.1016/j.ijhydene.2017.08.042",

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T1 - Influence of the architecture of Au–Ag–Pt nanoparticles on the electrocatalytic activity for hydrogen evolution reaction

AU - Londono-Calderon, A.

AU - Campos-Roldan, C. A.

AU - González-Huerta, R. G.

AU - Hernandez-Pichardo, M. L.

AU - del Angel, P.

AU - Yacaman, M. J.

PY - 2017

Y1 - 2017

N2 - In this work, Au–Ag–Pt and Au@AgPt yolk-shell nanoparticles were synthetized via chemical reduction and seed-mediated galvanic replacement method, in order to obtain two different architectures with the same metal content. The architecture influence on the electrocatalytic activity towards the hydrogen evolution reaction (HER) of these nanostructured materials was evaluated in acidic media. The hierarchical architecture allows a superior electrocatalytic activity towards hydrogen evolution mainly due to the synergetic effect between the exposed metals on the surface (Pt and Ag) and the higher availability of Pt allowed by the yolk-shell structure.

AB - In this work, Au–Ag–Pt and Au@AgPt yolk-shell nanoparticles were synthetized via chemical reduction and seed-mediated galvanic replacement method, in order to obtain two different architectures with the same metal content. The architecture influence on the electrocatalytic activity towards the hydrogen evolution reaction (HER) of these nanostructured materials was evaluated in acidic media. The hierarchical architecture allows a superior electrocatalytic activity towards hydrogen evolution mainly due to the synergetic effect between the exposed metals on the surface (Pt and Ag) and the higher availability of Pt allowed by the yolk-shell structure.

KW - Au@AgPt yolk-shell nanoparticles

KW - Au–Ag–Pt nanoparticles

KW - Hydrogen evolution reaction (HER)

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U2 - 10.1016/j.ijhydene.2017.08.042

DO - 10.1016/j.ijhydene.2017.08.042

M3 - Artículo

SN - 0360-3199

VL - 42

SP - 30208

EP - 30215

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 51

ER -

Influence of the architecture of Au–Ag–Pt nanoparticles on the electrocatalytic activity for hydrogen evolution reaction

Abstract

Keywords

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