Inducing magnetic communication in caged dinuclear Co(ii) systems

Judith Caballero-Jiménez, Fatemah Habib, Daniel Ramírez-Rosales, Rafael Grande-Aztatzi, Gabriel Merino, Ilia Korobkov, Mukesh Kumar Singh, Gopalan Rajaraman, Yasmi Reyes-Ortega, Muralee Murugesu

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© 2015 The Royal Society of Chemistry. The synthesis, structural, electronic and magnetic characterization of five dinuclear Co(ii) azacryptand compounds (1-5) bridged through different ions are reported. The magnetic exchange interactions, 2J values, obtained from theoretical computations show that the variation of the intermetallic angles and distances lead to antiferromagnetic behaviours. Magneto-structural correlations show a trend, where the angles Co(ii)-bridge-Co(ii) closer to 180° favour an increase in the superexchange pathway leading to higher AF interaction values.
Original languageAmerican English
Pages (from-to)8649-8659
Number of pages7783
JournalDalton Transactions
StatePublished - 14 May 2015

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    Caballero-Jiménez, J., Habib, F., Ramírez-Rosales, D., Grande-Aztatzi, R., Merino, G., Korobkov, I., Singh, M. K., Rajaraman, G., Reyes-Ortega, Y., & Murugesu, M. (2015). Inducing magnetic communication in caged dinuclear Co(ii) systems. Dalton Transactions, 8649-8659.