The in situ formation of magnetoplumbite-type (M-type) hexaferrites within a 3Y-TZP matrix was examined for the La2O3-ZnO-Fe2O3 and BaO-Fe2O3 systems. The formation of barium hexaferrite (Ba-M) was rapid enough at a temperature of 1300 °C for 2 h to result in a uniform dispersion of fine Ba-M particles in a tetragonal zirconia polycrystal (TZP) matrix. However, the formation of lanthanum-substituted hexaferrite (La-M) was rather sluggish, despite the existence of a charge-compensating divalent oxide. The 3Y-TZP/20-wt%-BaFe12O19 in situ composite possessed good magnetic properties, as well as moderately good mechanical properties.
|Original language||American English|
|Number of pages||1210|
|Journal||Journal of the American Ceramic Society|
|State||Published - 1 Jan 2000|
Suzuki, Y., Calderón, H. A., Kondo, N., & Ohji, T. (2000). In situ formation of hexaferrite magnets within a 3Y-TZP matrix: La<inf>2</inf>O<inf>3</inf>-ZnO-Fe<inf>2</inf>O<inf>3</inf> and BaO-Fe<inf>2</inf>O<inf>3</inf> systems. Journal of the American Ceramic Society, 1346-1350.