TY - JOUR
T1 - Improved Pd electro-catalysis for oxygen reduction reaction in direct methanol fuel cell by reduced graphene oxide
AU - Carrera-Cerritos, R.
AU - Baglio, V.
AU - Aricò, A. S.
AU - Ledesma-García, J.
AU - Sgroi, M. F.
AU - Pullini, D.
AU - Pruna, A. J.
AU - Mataix, D. B.
AU - Fuentes-Ramírez, R.
AU - Arriaga, L. G.
N1 - Funding Information:
Financial support from the European Commission FP7/2011-2014 , grant agreement GRENADA No. 246073 , and from the Fuel Cells and Hydrogen Joint Technology Initiative , grant agreement DURAMET No. 278054 , is acknowledged. R. Carrera-Cerritos also thanks CONACYT for the Ph.D. Grant No. 213850. The authors gratefully acknowledge to Mexican Council for Science and Technology (CONACYT) through REDES TEMÁTICAS (Grant 193974).
PY - 2014/1
Y1 - 2014/1
N2 - Noble metallic nano-catalysts supported on carbon based substrates are extensively used as electrodes for direct methanol fuel cells (DMFCs). Pd is a promising alternative to the more expensive Pt whether its catalytic properties should be improved. To this aim, reduced graphene oxide (rGO) was employed in this study as an alternative to conventional carbon black (C) substrates to improve the catalytic properties of Pd. Pd nanobars and Pt nanoparticles were synthesized, by the polyol method, and deposited for comparison both on commercial carbon and rGO. The oxygen reduction reactions (ORRs) at the fabricated electrodes were tested by the Rotating Disk Electrode (RDE) technique in acidic media. To correlate the activity to other physico-chemical properties, the nano-catalysts were characterized by Thermo Gravimetric Analysis (TGA), X-Ray Diffraction (XRD), and Transmission Electron Microscopy (TEM). The electro-catalytic activity of the electrode is importantly affected by the support chosen. Specifically, the Pd nano-catalyst proved an enhanced performance when on rGO, while the Pt counterpart was found being more active when placed on C. This result can be explained with a strong dependence of the ORR on the interaction between the metal nano-catalyst and the carbon based support.
AB - Noble metallic nano-catalysts supported on carbon based substrates are extensively used as electrodes for direct methanol fuel cells (DMFCs). Pd is a promising alternative to the more expensive Pt whether its catalytic properties should be improved. To this aim, reduced graphene oxide (rGO) was employed in this study as an alternative to conventional carbon black (C) substrates to improve the catalytic properties of Pd. Pd nanobars and Pt nanoparticles were synthesized, by the polyol method, and deposited for comparison both on commercial carbon and rGO. The oxygen reduction reactions (ORRs) at the fabricated electrodes were tested by the Rotating Disk Electrode (RDE) technique in acidic media. To correlate the activity to other physico-chemical properties, the nano-catalysts were characterized by Thermo Gravimetric Analysis (TGA), X-Ray Diffraction (XRD), and Transmission Electron Microscopy (TEM). The electro-catalytic activity of the electrode is importantly affected by the support chosen. Specifically, the Pd nano-catalyst proved an enhanced performance when on rGO, while the Pt counterpart was found being more active when placed on C. This result can be explained with a strong dependence of the ORR on the interaction between the metal nano-catalyst and the carbon based support.
KW - Oxygen reduction reaction
KW - Pd nanobars
KW - Pt nanoparticles
KW - Reduced graphene oxide
UR - http://www.scopus.com/inward/record.url?scp=84882951895&partnerID=8YFLogxK
U2 - 10.1016/j.apcatb.2013.07.057
DO - 10.1016/j.apcatb.2013.07.057
M3 - Artículo
SN - 0926-3373
VL - 144
SP - 554
EP - 560
JO - Applied Catalysis B: Environmental
JF - Applied Catalysis B: Environmental
ER -