Effect of the water of crystallization on the Mössbauer spectra of hexacyanoferrates (II and III)

E. Reguera, J. Fernández-Bertrán

Research output: Contribution to journalArticle

30 Scopus citations

Abstract

Mössbauer spectra were recorded on hydrated, dehydrated and rehydrated hexacyanoferrate (II and III) samples including alkaline, alkaline-earth, transition metal and rare-earth salts. The location of the water molecules around the complex hexacyanoferrate anion has a decisive role on the quadrupole splitting of the low-spin Fe III cation. © 1994 J.C. Baltzer AG, Science Publishers.
Original languageAmerican English
Pages (from-to)49-58
Number of pages10
JournalHyperfine Interactions
DOIs
StatePublished - 1 Dec 1994
Externally publishedYes

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