Abstract
Mössbauer spectra were recorded on hydrated, dehydrated and rehydrated hexacyanoferrate (II and III) samples including alkaline, alkaline-earth, transition metal and rare-earth salts. The location of the water molecules around the complex hexacyanoferrate anion has a decisive role on the quadrupole splitting of the low-spin FeIII cation.
Original language | English |
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Pages (from-to) | 49-58 |
Number of pages | 10 |
Journal | Hyperfine Interactions |
Volume | 88 |
Issue number | 1 |
DOIs | |
State | Published - Dec 1994 |
Externally published | Yes |