TY - JOUR
T1 - Effect of copper, sulfur, arsenic and antimony on silver distribution in phases of lead blast furnace
AU - Chaidez-Felix, J.
AU - Romero-Serrano, A.
AU - Hernandez-Ramirez, A.
AU - Perez-Labra, M.
AU - Almaguer-Guzman, I.
AU - Benavides-Perez, R.
AU - Flores-Favela, M.
PY - 2014/4
Y1 - 2014/4
N2 - An experimental study was carried out to estimate the effect of the lead impurities on the silver distribution in the phases formed in the lead blast furnace. Samples of sinter with different contents of Cu, S, As and Sb were equilibrated under reducing atmosphere (p(CO)/p(CO2)=2.45) at 1573 K in a tube furnace and slowly cooled. The samples were characterized by scanning electron microscopy and microanalysis (SEM-EDS). There were five immiscible phases: slag (CaO, FeO and SiO2), matte (S, Cu and Fe), speiss (As, Fe and Cu), Cu-Sb phase and lead bullion (Pb, Ag, Sb, Cu, etc). The results showed that Cu and Sb promote silver losses during the process since they form a liquid solution with higher silver solubility than liquid bullion. Sulfur and arsenic react with copper to form the matte and speiss phases, respectively. The effect of S and As is to reduce the amount of Cu-Sb alloy and then the silver losses from the bullion.
AB - An experimental study was carried out to estimate the effect of the lead impurities on the silver distribution in the phases formed in the lead blast furnace. Samples of sinter with different contents of Cu, S, As and Sb were equilibrated under reducing atmosphere (p(CO)/p(CO2)=2.45) at 1573 K in a tube furnace and slowly cooled. The samples were characterized by scanning electron microscopy and microanalysis (SEM-EDS). There were five immiscible phases: slag (CaO, FeO and SiO2), matte (S, Cu and Fe), speiss (As, Fe and Cu), Cu-Sb phase and lead bullion (Pb, Ag, Sb, Cu, etc). The results showed that Cu and Sb promote silver losses during the process since they form a liquid solution with higher silver solubility than liquid bullion. Sulfur and arsenic react with copper to form the matte and speiss phases, respectively. The effect of S and As is to reduce the amount of Cu-Sb alloy and then the silver losses from the bullion.
KW - lead blast furnace
KW - lead impurities
KW - silver
UR - http://www.scopus.com/inward/record.url?scp=84900461443&partnerID=8YFLogxK
U2 - 10.1016/S1003-6326(14)63180-0
DO - 10.1016/S1003-6326(14)63180-0
M3 - Artículo
SN - 1003-6326
VL - 24
SP - 1202
EP - 1209
JO - Transactions of Nonferrous Metals Society of China (English Edition)
JF - Transactions of Nonferrous Metals Society of China (English Edition)
IS - 4
ER -