Control of the diels-alder addition regioselectivity by remote substituents. Synthesis of anthracycline precursors.

Joaquin Tamariz; Luis Schwager; John H.A. Stibbard; Pierre Vogel

doi:10.1016/S0040-4039(00)81691-3

Control of the diels-alder addition regioselectivity by remote substituents. Synthesis of anthracycline precursors.

Joaquin Tamariz, Luis Schwager, John H.A. Stibbard, Pierre Vogel

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The 2,3,5-tris (methylene)norbornane adds to methyl propynoate with "para" regioselectivity. This principle is applied to the regioselective synthesis of a daunomycinone precursor.

Original language	English
Pages (from-to)	1497-1500
Number of pages	4
Journal	Tetrahedron Letters
Volume	24
Issue number	14
DOIs	https://doi.org/10.1016/S0040-4039(00)81691-3
State	Published - 1983
Externally published	Yes

Access to Document

10.1016/S0040-4039(00)81691-3

Cite this

@article{863d61453162465bb1cd5875911ce743,

title = "Control of the diels-alder addition regioselectivity by remote substituents. Synthesis of anthracycline precursors.",

abstract = "The 2,3,5-tris (methylene)norbornane adds to methyl propynoate with {"}para{"} regioselectivity. This principle is applied to the regioselective synthesis of a daunomycinone precursor.",

author = "Joaquin Tamariz and Luis Schwager and Stibbard, {John H.A.} and Pierre Vogel",

note = "Funding Information: and was supported by MO calculations 4,6 .",

year = "1983",

doi = "10.1016/S0040-4039(00)81691-3",

language = "Ingl{\'e}s",

volume = "24",

pages = "1497--1500",

journal = "Tetrahedron Letters",

issn = "0040-4039",

number = "14",

}

TY - JOUR

T1 - Control of the diels-alder addition regioselectivity by remote substituents. Synthesis of anthracycline precursors.

AU - Tamariz, Joaquin

AU - Schwager, Luis

AU - Stibbard, John H.A.

AU - Vogel, Pierre

N1 - Funding Information: and was supported by MO calculations 4,6 .

PY - 1983

Y1 - 1983

N2 - The 2,3,5-tris (methylene)norbornane adds to methyl propynoate with "para" regioselectivity. This principle is applied to the regioselective synthesis of a daunomycinone precursor.

AB - The 2,3,5-tris (methylene)norbornane adds to methyl propynoate with "para" regioselectivity. This principle is applied to the regioselective synthesis of a daunomycinone precursor.

UR - http://www.scopus.com/inward/record.url?scp=49049126229&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)81691-3

DO - 10.1016/S0040-4039(00)81691-3

M3 - Artículo

SN - 0040-4039

VL - 24

SP - 1497

EP - 1500

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 14

ER -

Control of the diels-alder addition regioselectivity by remote substituents. Synthesis of anthracycline precursors.

Abstract

Access to Document

Other files and links

Fingerprint

Cite this