Compositional and Moisture Content Effects on the Biodegradability of Zein/Ethylcellulose Films

Claudia A. Romero-Bastida, Eduardo Flores-Huicochea, Martha O. Martin-Polo, Gonzalo Velazquez, J. Antonio Torres

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

The effect of moisture content and film composition on biodegradability is the focus of this study. Flexible films were first characterized for the effect on water sorption isotherms of relative humidity, temperature, zein content, and the addition of the plasticizers stearic acid, poly(ethylene glycol), or etoxylated ricine oil. Zein/ethylcellulose (EC) mixture films had a behavior between that for pure zein and EC films, which had the lowest water sorption. For films with plasticizer, the lowest water sorption at 25 °C was observed for those with stearic acid. Biodegradability of zein/EC films, evaluated using bacterial cultures selected for their zein proteolytic activity and isolated from a local solid waste landfill and a lagoon, showed no plasticizer effect even though its effect on moisture content was significant. Large differences were observed at different film zein concentration with the highest biodegradability for 100% zein. However, biodegradability did not mimic the water sorption behavior of zein/EC mixture films.

Original languageEnglish
Pages (from-to)2230-2235
Number of pages6
JournalJournal of Agricultural and Food Chemistry
Volume52
Issue number8
DOIs
StatePublished - 21 Apr 2004

Keywords

  • Biodegradability
  • Ethylcellulose
  • Moisture sorption isotherms
  • Plasticizer
  • Zein

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