Chalcopyrite Leaching Kinetics in the Presence of Methanol

O. J. Solís Marcial, A. Nájera Bastida, J. E. Bañuelos, O. U. Valdés Martínez, L. A. Luevano, B. Serrano Rosales

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6 Scopus citations

Abstract

The dissolution of chalcopyrite under near ambient conditions represents one of the main challenges in the copper industry. Thus, various routes have been proposed for chalcopyrite treatment, such as the use of polar organic solvents, and this has shown promising results. In this paper, we present a study of copper leaching from a chalcopyrite concentrate in aqueous acidic medium with methanol and various H2O2 concentrations at 15, 30, and 40â°C. The results show that nearly complete copper extraction was attained within 5âh at 40â°C. The extraction percentages were plotted as functions of time at each temperature. The experimental data were modeled using the shrinking core model considering the cylindrical particle shape (shrinking cylinder model) within acceptable confidence levels, yielding an estimated activation energy of 24.3âkJ/mol. Furthermore, the process was dependent on the H2O2 concentration, and it acts as a reagent rather than an oxidant in the leaching reaction. It was found that sulfur is the only species present in the solid phase formed during the leaching of chalcopyrite, demonstrating the co-dissolution of both copper and iron.

Original languageEnglish
Article number20190081
JournalInternational Journal of Chemical Reactor Engineering
Volume17
Issue number12
DOIs
StatePublished - 1 Dec 2019

Keywords

  • chalcopyrite
  • hydrogen peroxide
  • leaching
  • methanol
  • shrinking core model

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