TY - JOUR
T1 - CdTe solar cell degradation studies with the use of CdS as the window material
AU - Mendoza-Pérez, R.
AU - Sastre-Hernández, J.
AU - Contreras-Puente, G.
AU - Vigil-Galán, O.
N1 - Funding Information:
This work was supported by CONACYT with Project no. 47587.
PY - 2009/1
Y1 - 2009/1
N2 - We present in this work the degradation effects with time in thin film CdTe/CdS solar cells, where the CdS and CdTe layers are deposited by chemical bath deposition (CBD) and close space vapor transport (CSVT), respectively. The CdS thin films were grown from different baths by varying the S/Cd ratio. The variation of the S/Cd ratio allowed us to control the morphology and the density of defects, thus giving rise to better quality CBD CdS films. Depending on the S/Cd ratio an improvement of the morphology and capacitance signal was observed, these factors have also an influence on the open-circuit voltage, short-circuit current density, fill factor and conversion efficiency of the solar cell. The variation with time of these parameters in our devices was tracked during a period of 3 years measured directly on the exposed back contact regions (CdTe/Cu/Au). A discussion on the deterioration of the photovoltaic (PV) performance of the solar cells is presented in correlation with the local environmental conditions. This particular environment has contamination, and represents another type of stress for standard PV operations. These conditions reduce the mean life time of solar cells beyond short periods; this can be of interest for PV community.
AB - We present in this work the degradation effects with time in thin film CdTe/CdS solar cells, where the CdS and CdTe layers are deposited by chemical bath deposition (CBD) and close space vapor transport (CSVT), respectively. The CdS thin films were grown from different baths by varying the S/Cd ratio. The variation of the S/Cd ratio allowed us to control the morphology and the density of defects, thus giving rise to better quality CBD CdS films. Depending on the S/Cd ratio an improvement of the morphology and capacitance signal was observed, these factors have also an influence on the open-circuit voltage, short-circuit current density, fill factor and conversion efficiency of the solar cell. The variation with time of these parameters in our devices was tracked during a period of 3 years measured directly on the exposed back contact regions (CdTe/Cu/Au). A discussion on the deterioration of the photovoltaic (PV) performance of the solar cells is presented in correlation with the local environmental conditions. This particular environment has contamination, and represents another type of stress for standard PV operations. These conditions reduce the mean life time of solar cells beyond short periods; this can be of interest for PV community.
KW - CdS/CdTe
KW - Degradation
KW - Efficiency
KW - Solar cells
UR - http://www.scopus.com/inward/record.url?scp=56349154942&partnerID=8YFLogxK
U2 - 10.1016/j.solmat.2008.09.016
DO - 10.1016/j.solmat.2008.09.016
M3 - Artículo
SN - 0927-0248
VL - 93
SP - 79
EP - 84
JO - Solar Energy Materials and Solar Cells
JF - Solar Energy Materials and Solar Cells
IS - 1
ER -