Bis(diphenylphosphanyl)amine and its disulfide and diselenide. Application of the INEPT-HEED pulse sequence for measurement of 1 J(31P,15N) and isotope induced chemical shifts 1Δ14/15N(31P) at natural abundance of 15N

Bernd Wrackmeyer, Efren Garcia-Baez, Franciso J. Zuno-Cruz, Gloria Sanchez-Cabrera, Maria J. Rosales

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8 Citations (Scopus)

Abstract

Bis(diphenylphosphanyl)amine (1), the disulfide 1S and diselenide 1Se were selected to show the efficient application of the INEPT-HEED pulse sequence for measuring coupling constants 1 J(31 P,3115N) and isotope induced chemical shifts 1 Δ14/15N(31P), both at natural abundance of 15N, from 31P NMR spectra. The sign of 1 J(31P,15N) (> 0) in all three compounds was determined by selective heteronuclear 1H{31P} double resonance experiments.
Original languageAmerican English
Pages (from-to)185-188
Number of pages166
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
StatePublished - 1 Feb 2000
Externally publishedYes

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High energy electron diffraction
Chemical shift
Isotopes
Disulfides
Amines
Nuclear magnetic resonance
Experiments

Cite this

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title = "Bis(diphenylphosphanyl)amine and its disulfide and diselenide. Application of the INEPT-HEED pulse sequence for measurement of 1 J(31P,15N) and isotope induced chemical shifts 1Δ14/15N(31P) at natural abundance of 15N",
abstract = "Bis(diphenylphosphanyl)amine (1), the disulfide 1S and diselenide 1Se were selected to show the efficient application of the INEPT-HEED pulse sequence for measuring coupling constants 1 J(31 P,3115N) and isotope induced chemical shifts 1 Δ14/15N(31P), both at natural abundance of 15N, from 31P NMR spectra. The sign of 1 J(31P,15N) (> 0) in all three compounds was determined by selective heteronuclear 1H{31P} double resonance experiments.",
author = "Bernd Wrackmeyer and Efren Garcia-Baez and Zuno-Cruz, {Franciso J.} and Gloria Sanchez-Cabrera and Rosales, {Maria J.}",
year = "2000",
month = "2",
day = "1",
language = "American English",
pages = "185--188",
journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",
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TY - JOUR

T1 - Bis(diphenylphosphanyl)amine and its disulfide and diselenide. Application of the INEPT-HEED pulse sequence for measurement of 1 J(31P,15N) and isotope induced chemical shifts 1Δ14/15N(31P) at natural abundance of 15N

AU - Wrackmeyer, Bernd

AU - Garcia-Baez, Efren

AU - Zuno-Cruz, Franciso J.

AU - Sanchez-Cabrera, Gloria

AU - Rosales, Maria J.

PY - 2000/2/1

Y1 - 2000/2/1

N2 - Bis(diphenylphosphanyl)amine (1), the disulfide 1S and diselenide 1Se were selected to show the efficient application of the INEPT-HEED pulse sequence for measuring coupling constants 1 J(31 P,3115N) and isotope induced chemical shifts 1 Δ14/15N(31P), both at natural abundance of 15N, from 31P NMR spectra. The sign of 1 J(31P,15N) (> 0) in all three compounds was determined by selective heteronuclear 1H{31P} double resonance experiments.

AB - Bis(diphenylphosphanyl)amine (1), the disulfide 1S and diselenide 1Se were selected to show the efficient application of the INEPT-HEED pulse sequence for measuring coupling constants 1 J(31 P,3115N) and isotope induced chemical shifts 1 Δ14/15N(31P), both at natural abundance of 15N, from 31P NMR spectra. The sign of 1 J(31P,15N) (> 0) in all three compounds was determined by selective heteronuclear 1H{31P} double resonance experiments.

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JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

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