Aquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying

G. J. Gutiérrez Paredes, J. N. Rivera Olvera, A. López Villa, L. Díaz Barriga Arceo

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

© Springer International Publishing Switzerland 2016. MoWC-NiC-WC was produced by mechanical alloying at the following grinding times: 0, 40, 80, 120, 160, 200 and 240 h. XRD results indicated that by increasing the milling time from 0 to 240 h, the nanostructured carbide phases were synthesized with a crystal size ranging from 125.6 to 10.1 nm. The performance of the nano-catalysts in the heavy oil before and after the reaction was analyzed by Fourier transform infrared spectroscopy (FTIR), Viscosimetry, SARA method analysis by Thin-layer chromatography-flame ionization detection (TLC-FID), elemental (EL) analysis, and gas chromatography/mass spectroscopy (GC/MS). As the milling time increased, the ratio of the viscosity reduction of the heavy oil increased from 80.4 to 97.1 % by using the catalyst milled for 240 h. In addition, the results showed that some reactions were observed during the aquathermolysis: pyrolysis, depolymerization, hydrogenation, isomerization, ring opening, desulphurization, etc. It was also found that the catalysts at short milling times caused more changes in the resin, saturated hydrocarbon, and oxygen-containing groups, whereas the 240 h catalyst led to more changes in the asphaltene, aromatic hydrocarbon, and sulfur-containing groups.
Original languageAmerican English
Title of host publicationAquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying
Pages493-506
Number of pages442
ISBN (Electronic)9783319279640
DOIs
StatePublished - 1 Jan 2016
EventEnvironmental Science and Engineering (Subseries: Environmental Science) -
Duration: 1 Jan 2016 → …

Publication series

NameEnvironmental Science and Engineering (Subseries: Environmental Science)
ISSN (Print)1863-5520

Conference

ConferenceEnvironmental Science and Engineering (Subseries: Environmental Science)
Period1/01/16 → …

Fingerprint

Oils
Flame Ionization
Aromatic Hydrocarbons
Hydrogenation
Fourier Transform Infrared Spectroscopy
Thin Layer Chromatography
Hydrocarbons
Switzerland
Sulfur
Viscosity
Gas Chromatography
Mass Spectrometry
Oxygen

Cite this

Gutiérrez Paredes, G. J., Rivera Olvera, J. N., López Villa, A., & Díaz Barriga Arceo, L. (2016). Aquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying. In Aquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying (pp. 493-506). (Environmental Science and Engineering (Subseries: Environmental Science)). https://doi.org/10.1007/978-3-319-27965-7_35
Gutiérrez Paredes, G. J. ; Rivera Olvera, J. N. ; López Villa, A. ; Díaz Barriga Arceo, L. / Aquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying. Aquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying. 2016. pp. 493-506 (Environmental Science and Engineering (Subseries: Environmental Science)).
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Gutiérrez Paredes, GJ, Rivera Olvera, JN, López Villa, A & Díaz Barriga Arceo, L 2016, Aquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying. in Aquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying. Environmental Science and Engineering (Subseries: Environmental Science), pp. 493-506, Environmental Science and Engineering (Subseries: Environmental Science), 1/01/16. https://doi.org/10.1007/978-3-319-27965-7_35

Aquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying. / Gutiérrez Paredes, G. J.; Rivera Olvera, J. N.; López Villa, A.; Díaz Barriga Arceo, L.

Aquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying. 2016. p. 493-506 (Environmental Science and Engineering (Subseries: Environmental Science)).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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Gutiérrez Paredes GJ, Rivera Olvera JN, López Villa A, Díaz Barriga Arceo L. Aquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying. In Aquathemolysis reaction of heavy oil by a mownic nanocrystalline catalyst produced by mechanical alloying. 2016. p. 493-506. (Environmental Science and Engineering (Subseries: Environmental Science)). https://doi.org/10.1007/978-3-319-27965-7_35