TY - JOUR
T1 - An improved ethanol microfluidic fuel cell based on a PdAg/MWCNT catalyst synthesized by the reverse micelles method
AU - Armenta-González, A. J.
AU - Carrera-Cerritos, R.
AU - Moreno-Zuria, A.
AU - Álvarez-Contreras, L.
AU - Ledesma-García, J.
AU - Cuevas-Muñiz, F. M.
AU - Arriaga, L. G.
N1 - Publisher Copyright:
© 2015 Elsevier Ltd. All rights reserved.
PY - 2016/3/1
Y1 - 2016/3/1
N2 - In this work, two electrocatalysts based on Pd (Pd/MWCNT and PdAg/MWCNT) were synthesized using reverse micelles for ethanol oxidation (EOR), and evaluated in an air-breathing microfluidic fuel cell. Commercial Pd (Pd/C) was used for comparison. The average nanoparticle size estimated by TEM was approximately 4-7 nm for both electrocatalysts. TGA measurements indicated that the electrocatalysts had similar metallic loading (19% for Pd and 17% for PdAg). The materials were tested for EOR in 1 M KOH. Fuel cell tests were performed in an air-breathing microfluidic fuel cell (ABμFFC) in which oxygen was obtained from the air to improve the performance of the cathodic reaction. The results were compared with those obtained using a closed microfluidic fuel cell (μFFC). In these devices, two streams were injected, one containing fuel and the other containing an electrolyte solution (1 M KOH), and commercial Pt (Pt/C) was used as cathodic catalyst. The ABμFFC that used the PdAg/MWCNT electrocatalyst performed better (almost 70% more power was harvested) than the one that used the Pd/MWCNT electrocatalyst. Finally, the power density harvested from the ABμFFC was 4 times higher than that harvested from the μFFC.
AB - In this work, two electrocatalysts based on Pd (Pd/MWCNT and PdAg/MWCNT) were synthesized using reverse micelles for ethanol oxidation (EOR), and evaluated in an air-breathing microfluidic fuel cell. Commercial Pd (Pd/C) was used for comparison. The average nanoparticle size estimated by TEM was approximately 4-7 nm for both electrocatalysts. TGA measurements indicated that the electrocatalysts had similar metallic loading (19% for Pd and 17% for PdAg). The materials were tested for EOR in 1 M KOH. Fuel cell tests were performed in an air-breathing microfluidic fuel cell (ABμFFC) in which oxygen was obtained from the air to improve the performance of the cathodic reaction. The results were compared with those obtained using a closed microfluidic fuel cell (μFFC). In these devices, two streams were injected, one containing fuel and the other containing an electrolyte solution (1 M KOH), and commercial Pt (Pt/C) was used as cathodic catalyst. The ABμFFC that used the PdAg/MWCNT electrocatalyst performed better (almost 70% more power was harvested) than the one that used the Pd/MWCNT electrocatalyst. Finally, the power density harvested from the ABμFFC was 4 times higher than that harvested from the μFFC.
KW - Air-breathing FC
KW - Alcohol fuel cell
KW - Bimetallic electrocatalyst
KW - Ethanol electro-oxidation
UR - http://www.scopus.com/inward/record.url?scp=84949257079&partnerID=8YFLogxK
U2 - 10.1016/j.fuel.2015.11.057
DO - 10.1016/j.fuel.2015.11.057
M3 - Artículo
SN - 0016-2361
VL - 167
SP - 240
EP - 247
JO - Fuel
JF - Fuel
ER -