TY - JOUR
T1 - 2-phenyl-2-(p-tosylamino)acetic acid, a versatile pro-ligand for organotin compounds
AU - Duarte-Hernández, Angélica M.
AU - Montes-Tolentino, Pedro
AU - Ramos-García, Iris
AU - Ramos-Organillo, Ángel
AU - Villaseñor-Granados, Tayde
AU - Suárez-Moreno, Galdina V.
AU - Contreras, Rosalinda
AU - Flores-Parra, Angelina
N1 - Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2017
Y1 - 2017
N2 - Herein we report the synthesis and structural study of ten new tin compounds derived from the polyfunctional and optically active pro-ligand: 2-phenyl-2-(p-tosylsuphonamino)acetic acid (1). Reactions of the sodium carboxylate of compound 1 with SnMe2Cl2; SnPh2Cl2, SnMe3Cl, SnPh3Cl and that of 1 with nBu2SnO in benzene were investigated. Structures of the reaction products {chloro(dimethyl)tin [(S) 2-phenyl-2-(p-tolylamino)]acetate (2), trimethyltin [(S) 2-phenyl-2-(p-tolylamino)]acetate (3), triphenyltin (S) 2-phenyl-2-(4-methylphenylamino)acetate (4), dimethyltin bis-[2-phenyl-2-(p-tolylamino) acetate] (5), chlorophenyltin bis-[2-phenyl-2-(p-tolylamino)acetate] (6), diphenyltin bis-[2-phenyl-2-(p-tolylamino)acetate] (7) and aqua-dinbutyltin bis-[2-phenyl-2-(p-tolylamino) acetate] (8)} were determined by NMR and high resolution mass spectrometry. Two crystals from compound 3 (3a and 3b), one from aqua-diphenyltin bis-[2-phenyl-2-(p-tolylamino)acetate] (9) and one from dinbutyl-distannoxane tetra[2-phenyl-2-(p-tolylamino)acetate] (10) were analysed by X-ray diffraction. The new compounds are hypervalent; 2–4 are pentacoordinated, 5–7 are hexacoordinated whereas 8 and 9 are heptacoordinated. Theoretical study of compounds 2, 3, and the model compounds: dimethyltin bis-acetate, diphenyltin bis-acetate and their water complexes was performed by B3LYP/LANL2DZ base calculations, particularly O⋯O interaction through the space.
AB - Herein we report the synthesis and structural study of ten new tin compounds derived from the polyfunctional and optically active pro-ligand: 2-phenyl-2-(p-tosylsuphonamino)acetic acid (1). Reactions of the sodium carboxylate of compound 1 with SnMe2Cl2; SnPh2Cl2, SnMe3Cl, SnPh3Cl and that of 1 with nBu2SnO in benzene were investigated. Structures of the reaction products {chloro(dimethyl)tin [(S) 2-phenyl-2-(p-tolylamino)]acetate (2), trimethyltin [(S) 2-phenyl-2-(p-tolylamino)]acetate (3), triphenyltin (S) 2-phenyl-2-(4-methylphenylamino)acetate (4), dimethyltin bis-[2-phenyl-2-(p-tolylamino) acetate] (5), chlorophenyltin bis-[2-phenyl-2-(p-tolylamino)acetate] (6), diphenyltin bis-[2-phenyl-2-(p-tolylamino)acetate] (7) and aqua-dinbutyltin bis-[2-phenyl-2-(p-tolylamino) acetate] (8)} were determined by NMR and high resolution mass spectrometry. Two crystals from compound 3 (3a and 3b), one from aqua-diphenyltin bis-[2-phenyl-2-(p-tolylamino)acetate] (9) and one from dinbutyl-distannoxane tetra[2-phenyl-2-(p-tolylamino)acetate] (10) were analysed by X-ray diffraction. The new compounds are hypervalent; 2–4 are pentacoordinated, 5–7 are hexacoordinated whereas 8 and 9 are heptacoordinated. Theoretical study of compounds 2, 3, and the model compounds: dimethyltin bis-acetate, diphenyltin bis-acetate and their water complexes was performed by B3LYP/LANL2DZ base calculations, particularly O⋯O interaction through the space.
KW - 2-phenyl-2-(p-tosylsuphonamino)acetic acid
KW - Hypervalent tin carboxylates
KW - Spectroscopic and theoretical studies
KW - Weak interactions
UR - http://www.scopus.com/inward/record.url?scp=85007190260&partnerID=8YFLogxK
U2 - 10.1016/j.jorganchem.2016.12.022
DO - 10.1016/j.jorganchem.2016.12.022
M3 - Artículo
SN - 0022-328X
VL - 830
SP - 120
EP - 130
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
ER -